N-tosyl-2,4-dimethyl-8-aminoquinoline | 849003-27-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-tosyl-2,4-dimethyl-8-aminoquinoline
• 英文别名: N-(2,4-dimethylquinolin-8-yl)-4-methylbenzenesulfonamide
• CAS: 849003-27-6
• 化学式: C₁₈H₁₈N₂O₂S
• 分子量: 326.419
• InChiKey: AWEBDEOGYSQMIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  67.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Ni9(HOOCCMe3)4(μ4-OH)3(μ(3)-OH)3(μ(n)-OOCCMe3)12 、 N-tosyl-2,4-dimethyl-8-aminoquinoline 、 乙腈 以 乙腈 为溶剂， 以43%的产率得到bis(N-tosyl-2,4-dimethyl-8-amidoquinolino)nickel(II)*3 acetonitrile
  参考文献：
  名称：

  Influence of intermolecular hydrogen bonding on magnetic properties of mononuclear cobalt and nickel pivalates with amidine ligands

  摘要：

  The magnetic properties of the mononuclear cobalt(ii) amidine complex Co(Me3CCOO)(2){H2N(C5H3N)NH(MeC=NH (1) having a tetrahedral structure and its solvate 1-HOOCCMe3.0.5C(6)H(6) (1a) are substantially different. Complex 1 possesses ferromagnetic properties and exhibits residual magnetization at liquid-helium temperatures, whereas solvate la and the octahedral amidine complex Ni(Me3CCOO)(2)(H2N(C5H3N)NH(MeC=NH}.MeCN (3.MeCN) show antiferromagnetic properties. Apparently, this is associated with the difference in the type of intermolecular nonbonded interactions in the crystals of 1, 1a, and 3 . MeCN, which form channels for spin-spin exchange. The tetrahedral isostructural mononuclear complexes ML2 (M = Co (5), Ni (6), L is N-tosyl-2,5-dimethyl-8-aminoquinoline) were synthesized. These complexes exhibit antiferromagnetic properties.

  DOI：

  10.1023/b:rucb.0000046244.43123.98