[Rh2(N,N'-di-p-tolylformamidinate)2(4-cyanobenzoate)2] | 523999-80-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Rh2(N,N'-di-p-tolylformamidinate)2(4-cyanobenzoate)2]
• CAS: 523999-80-6
• 化学式: C₄₆H₃₈N₆O₄Rh₂
• 分子量: 944.657
• InChiKey: RDNYNJFIKWTSMK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  吡啶 、 [Rh2(N,N'-di-p-tolylformamidinate)2(4-cyanobenzoate)2] 以 苯 为溶剂， 以90%的产率得到[Rh2(N,N'-di-p-tolylformamidinate)2(4-cyanobenzoate)2(pyridine)2]
  参考文献：
  名称：

  New dirhodium(II,II) species as building corner connectors for square molecular boxes

  摘要：

  The new mixed dirhodium(II,II) complexes, [Rh-2(form)(2)(O2CC6H4CN)(2)] (2) and [Rh-2(form)(2)(O2CC5H4N)(2)] (3) (form = N,N'-di-p-tolylformamidinate) as building corner connectors for heteronuclear molecular boxes, were synthesized. By exploiting the peculiar equatorial reactivity of [Rh-2(form)(2)(O2CCF3)(2)(H2O)(2)] (1), due to the lability of trifluoroacetates, the synthesis of 2 and 3 was readily achieved by mathematical relations with the exo-functionalized 4-cyanobenzoate and isonicotinate carboxylates, respectively. The X-ray diffraction studies performed on the pyridine adduct of 2, [Rh-2(form)(2)(O2CC6H4CN)(2)(Py)(2)], are reported, together with some preliminary attempts of self-assembly with square-planar platinum(II) and palladium(II) complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01171-4
• 作为产物：
  描述：

  Rh2(N,N'-di-p-tolylformamidinate)2(trifluoroacetate)2(H2O)2 、 sodium 4-cyanobenzoate 以 氯仿 、 水 、 丙酮 为溶剂， 以90%的产率得到[Rh2(N,N'-di-p-tolylformamidinate)2(4-cyanobenzoate)2]
  参考文献：
  名称：

  New dirhodium(II,II) species as building corner connectors for square molecular boxes

  摘要：

  The new mixed dirhodium(II,II) complexes, [Rh-2(form)(2)(O2CC6H4CN)(2)] (2) and [Rh-2(form)(2)(O2CC5H4N)(2)] (3) (form = N,N'-di-p-tolylformamidinate) as building corner connectors for heteronuclear molecular boxes, were synthesized. By exploiting the peculiar equatorial reactivity of [Rh-2(form)(2)(O2CCF3)(2)(H2O)(2)] (1), due to the lability of trifluoroacetates, the synthesis of 2 and 3 was readily achieved by mathematical relations with the exo-functionalized 4-cyanobenzoate and isonicotinate carboxylates, respectively. The X-ray diffraction studies performed on the pyridine adduct of 2, [Rh-2(form)(2)(O2CC6H4CN)(2)(Py)(2)], are reported, together with some preliminary attempts of self-assembly with square-planar platinum(II) and palladium(II) complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01171-4