3,3'-<(1-Methylethylidene)bis(4,1-phenyleneoxy)>bis(2-chloro-2,3,3-trifluoropropanamide) | 131043-08-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-<(1-Methylethylidene)bis(4,1-phenyleneoxy)>bis(2-chloro-2,3,3-trifluoropropanamide)
• 英文别名: 3-[4-[2-[4-(3-amino-2-chloro-1,1,2-trifluoro-3-oxopropoxy)phenyl]propan-2-yl]phenoxy]-2-chloro-2,3,3-trifluoropropanamide
• CAS: 131043-08-8
• 化学式: C₂₁H₁₈Cl₂F₆N₂O₄
• 分子量: 547.281
• InChiKey: BULWPTBDNJHDTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.74
• 重原子数：
  35.0
• 可旋转键数：
  10.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  104.64
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  bisphenol A disodium salt 在 氨 作用下， 以 甲醇 为溶剂， 生成 3,3'-<(1-Methylethylidene)bis(4,1-phenyleneoxy)>bis(2-chloro-2,3,3-trifluoropropanamide)
  参考文献：
  名称：

  Fluorinated bifunctional derivatives of bisphenol A

  摘要：

  Bisphenol A reacted as its disodium salt with tetrafluoroethylene and carbon dioxide followed by dimethyl sulfate to give in high yield a symmetrical dimethyl ester assembled from seven structural elements. This diester was transformed into the corresponding diol, diamide, diamine, diisocyanate, and bis(methyl carbamate). Analogous diesters were prepared by using bisphenol A and chlorotrifluoroethylene as well as hexafluorobisphenol A and tetrafluoroethylene. Both of these esters were transformed into other bifunctional derivatives. Catalytic hydrogenation of the diol derived from bisphenol A and tetrafluoroethylene was accompanied by hydrogenolysis of the aryl-oxygen bonds.

  DOI：

  10.1021/jo00001a030

文献信息

• ARNOLD-STANTON, REGINA;LEMAL, DAVID M., J. ORG. CHEM., 56,(1991) N, C. 146-151
  作者：ARNOLD-STANTON, REGINA、LEMAL, DAVID M.

  DOI：——

  日期：——