carbanide;chloropalladium(1+);2-methyl-6-pyridin-2-ylpyridine | 369386-48-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: carbanide;chloropalladium(1+);2-methyl-6-pyridin-2-ylpyridine
• CAS: 369386-48-1
• 化学式: C₁₂H₁₃ClN₂Pd
• 分子量: 327.122
• InChiKey: KAFLTOXXDHXTMG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  carbanide;chloropalladium(1+);2-methyl-6-pyridin-2-ylpyridine 、 一氧化碳 以 二氯甲烷 为溶剂， 以91%的产率得到chloropalladium(1+);ethanone;2-methyl-6-pyridin-2-ylpyridine
  参考文献：
  名称：

  Synthesis and Molecular Structure of [Pd{CH₂CH₂C(O)Me}(HL)][BAr‘₄] (HL = 6-Me-2,2‘-bipyridine, Ar‘ = 3,5-(CF₃)₂C₆H₃), an Intermediate Relevant to Ethene/CO Copolymerization

  摘要：

  In the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr ' (4)] (HL = 6-Me-2,2 ' -bipyridine, Ar ' = 3,5-(CF3)(2)C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state.

  DOI：

  10.1021/om010278f
• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 6-甲基-2,2′-二吡啶 以 乙醚 、 苯 为溶剂， 以96%的产率得到carbanide;chloropalladium(1+);2-methyl-6-pyridin-2-ylpyridine
  参考文献：
  名称：

  Synthesis and Molecular Structure of [Pd{CH₂CH₂C(O)Me}(HL)][BAr‘₄] (HL = 6-Me-2,2‘-bipyridine, Ar‘ = 3,5-(CF₃)₂C₆H₃), an Intermediate Relevant to Ethene/CO Copolymerization

  摘要：

  In the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr ' (4)] (HL = 6-Me-2,2 ' -bipyridine, Ar ' = 3,5-(CF3)(2)C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state.

  DOI：

  10.1021/om010278f