5-(二对甲苯基氨基)-2-噻吩甲醛 | 98660-86-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 5-(二对甲苯基氨基)-2-噻吩甲醛
• 英文名称: 5-(di-p-tolylamino)thiophene-2-carbaldehyde
• 英文别名: 5-(4-methyl-N-(4-methylphenyl)anilino)thiophene-2-carbaldehyde
• CAS: 98660-86-7
• 化学式: C₁₉H₁₇NOS
• 分子量: 307.416
• InChiKey: KIDANXQJPSEATQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  48.6
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险性防范说明：
  P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313
• 危险性描述：
  H315,H319

反应信息

• 作为反应物：
  描述：

  5-(二对甲苯基氨基)-2-噻吩甲醛 、 2-(4-phenyl-5H-thiazol-2-ylidene)malononitrile 在 乙酸酐 作用下， 反应 8.0h， 以93%的产率得到2-{5-[(5,5-(di-p-tolylamino)thiophen-2-yl)methylene]-4-phenylthiazol-2(5H)-ylidene}malononitrile
  参考文献：
  名称：

  长波长吸收供体/受体取代次甲基染料的合成与表征

  摘要：

  摘要 通过芳族或杂芳族甲酰基化合物或其相应的亚胺盐与活性亚甲基化合物反应，制备了一系列在近红外光谱范围具有长波长吸收的新型次甲基染料。

  DOI：

  10.1515/znb-2016-0009

文献信息

• Miniaturization of molecular conjugated systems for organic solar cells: towards pigmy donors
  作者：Victorien Jeux、Dora Demeter、Philippe Leriche、Jean Roncali

  DOI：10.1039/c3ra40966j

  日期：——

  Organic solar cells with short-circuit current densities and conversion efficiencies of ca. 7.0 mA cm−2 and 2.0%, respectively, have been fabricated with a very small molecular donor based on substituted triarylamines.

  利用一种基于取代三芳基胺的极小分子供体，制造出了短路电流密度和转换效率分别约为 7.0 mA cm-2 和 2.0% 的有机太阳能电池。
• NOVEL COMPOUND, AND COMPOSITION FOR FORMING HOLE TRANSPORTING LAYER FOR PEROVSKITE SOLAR CELLS
  申请人：TOKYO CHEMICAL INDUSTRY CO., LTD.

  公开号：US20210319957A1

  公开（公告）日：2021-10-14

  Provided are: a composition for forming a hole transporting layer for perovskite solar cells, which is inexpensive and does not need to be used together with a dopant; and a compound which can be contained in a composition for forming a hole transporting layer. A compound represented by general formula (I) (wherein Ar represents an aryl group; A represents a structure represented by formula (II); Z's independently represent a hydrogen atom, a structure represented by general formula (III), or a structure represented by formula (IV), and maybe the same as or different from each other, wherein a case where each of Z's is a hydrogen atom is excluded; Y's independently represents at least one member selected from the group mentioned below; R 1 and R 2 independently represents a hydrogen atom, an alkyl group or an alkoxy group, or R 1 and R 2 may together form a ring having one or two oxygen atoms; ×'s independently represent an alkyl group, an alkoxy group, an alkylthio group, a monoalkylamino group or a dialkylamino group each of which may be substituted by a halogen atom; k represents 0 or 1; l represents 2 or 3; m represents an integer of 1 to 6; and r represents 1 or 2; wherein, when k is 0, 1 is 3, m is 1 and all of three bonds of A are bonded to Z.
• US4603097A
  申请人：——

  公开号：US4603097A

  公开（公告）日：1986-07-29
• US5072043A
  申请人：——

  公开号：US5072043A

  公开（公告）日：1991-12-10
• US5292896A
  申请人：——

  公开号：US5292896A

  公开（公告）日：1994-03-08