1,1,2,2-Tetrafluoro-2-[1,6,7,7,7-pentafluoro-6-(1,1,2,2-tetrafluoro-2-fluorosulfonyl-ethoxy)-1-trifluoromethyl-heptyloxy]-ethanesulfonyl fluoride | 135128-86-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 磺酰卤
• 英文名称: 1,1,2,2-Tetrafluoro-2-[1,6,7,7,7-pentafluoro-6-(1,1,2,2-tetrafluoro-2-fluorosulfonyl-ethoxy)-1-trifluoromethyl-heptyloxy]-ethanesulfonyl fluoride
• 英文别名: 1,1,2,2-tetrafluoro-2-[1,1,1,2,7,8,8,8-octafluoro-7-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)octan-2-yl]oxyethanesulfonyl fluoride
• CAS: 135128-86-8
• 化学式: C₁₂H₈F₁₈O₆S₂
• 分子量: 654.295
• InChiKey: VCERVCWZXILYHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.01
• 重原子数：
  38.0
• 可旋转键数：
  13.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86.74
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  乙烯 、 2,3,3,3-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)propanoic acid 以68%的产率得到
  参考文献：
  名称：

  CHERSTKOV, V. F.;GRINBERG, V. A.;STERLIN, S. R.;VASILEV, YU. B.;GERMAN, L+, IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1134-1141

  摘要：

  DOI：

文献信息

• Localization of electrochemically generated radicals as a function of their structure and the nature of the solvent
  作者：V. F. Cherstkov、V. A. Grinberg、S. R. Sterlin、Yu. B. Vasil'ev、L. S. German、E. I. Mysov

  DOI：10.1007/bf00961365

  日期：1991.5

  The electrooxidation of different perfluorocarboxylic acids has been investigated in the presence of ethylene, on electrodes with different adsorbing power [platinum and glassy carbon (GC)] in different solvents. It has been shown that the reaction zone of the ECG radicals is determined by their solubility; depending on this, it can be limited to the electrode surface or encompass the entire volume of the solution. The concept of the solubility of the ECG radicals made it possible to establish some regularities in the formation of cross combination products in the Kolbe electrosynthesis of different perfluorocarboxylic acids.