[Pt(piperidine)2(dimethylmalonato)] | 284671-34-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子
• 英文名称: [Pt(piperidine)2(dimethylmalonato)]
• 英文别名: 2,2-dimethylpropanedioate;piperidine;platinum(2+)
• CAS: 284671-34-7
• 化学式: C₁₅H₂₈N₂O₄Pt
• 分子量: 495.478
• InChiKey: JYMNXGKHVFPBMT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro-bis(piperidine)-platinum(II) dihydrate 以 水 为溶剂， 生成 [Pt(piperidine)2(dimethylmalonato)]
  参考文献：
  名称：

  Synthesis and characterization of piperidine platinum(II) complexes with dicarboxylates: crystal and molecular structure of cis-[Pt(piperidine)2Cl2]·H2O

  摘要：

  A series of new platinum complexes of the type cis-[Pt(PIP)(2)X] (where PIP = piperidine and X = dichloro, sulfate, oxalato, malonato, methylmalonato, dimethylmalonato, tartronato, 1,1-cyclopropyldicarboxylato (CPDCA) or 1,1-cyclobutyldicarboxylato (CBDCA) ligand) were synthesized and characterized by elemental analysis, IR, and Pt-195 nuclear magnetic resonance spectroscopy. The crystal structure of cis-[Pt(PIP)(2)Cl-2] . H2O was determined by X-ray crystallography. In this complex platinum has slightly distorted square planar geometry with two adjacent corners being occupied by two nitrogen atoms of piperidine, whereas the remaining two adjacent corners are occupied by two chloride atoms. An intricate network of intermolecular hydrogen bonding holds the crystal lattice together. In these complexes, piperidine acts as non-leaving ligand, whereas the dicarboxylic acids act as leaving groups. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00348-x