trans-Co(thiophenolo-p-chlorophenylglyoximate)2(H2O)2 | 475466-41-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-Co(thiophenolo-p-chlorophenylglyoximate)2(H2O)2
• CAS: 475466-41-2
• 化学式: C₂₈H₂₄Cl₂CoN₄O₆S₂
• 分子量: 706.553
• InChiKey: REPDAFJUTRRCBQ-VZYZIFQBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 thiophenolo-p-chlorophenylglyoxime 、 水 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以75%的产率得到trans-Co(thiophenolo-p-chlorophenylglyoximate)2(H2O)2
  参考文献：
  名称：

  SYNTHESIS AND COMPLEX FORMATION OF UNSYMMETRICALLY SUBSTITUTED ARYLTHIO-p-CHLOROPHENYLvic-DIOXIMES

  摘要：

  anti-Chlorophenylchloroglyoxime, 4-ClC6H4C=NOH)CCl(=NOH), has been synthesized by chlorination of anti-p-cholorophenylglyoxime. The reaction. of 4-ClC6H4C(=NOH)CCl(=NOH) with thiophenol, 4-methylthiophenol and 4-methoxythiophenol in ethanol between -5 and -10degreesC gives the unsymmetrical vic-dioximes, designated as thiophenolo-p-chlorophenylglyoxime, 4-ClC6H4C(=NOH)C(SC6H5)(=NOH), 4-methylthiophenolo-p-chlorophenylglyoxime, 4-ClC6H4C(=NOH)C(SC6H4-CH3-p)(=NOH), and 4-methoxylthiophenolo-p-chlorophenylglyoxime, 4-ClC6H4C(=NOH)C(SC6H4-OCH3-p)(=NOH). The Cu(II) and Ni(II) complexes of these ligands were prepared and are proposed to be square-planar, while the corresponding Co(II) complexes are proposed to be octahedral with water molecules as axial ligands. The structural assiguments are supported by H-1 NMR, IR and elemental analyses.

  DOI：

  10.1081/sim-120005619