4,4'-bis[4-(diphenylamino)phenyl]-1,1'-binaphthyl | 1238379-35-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4,4'-bis[4-(diphenylamino)phenyl]-1,1'-binaphthyl
• 英文别名: N,N-diphenyl-4-[4-[4-[4-(N-phenylanilino)phenyl]naphthalen-1-yl]naphthalen-1-yl]aniline
• CAS: 1238379-35-5
• 化学式: C₅₆H₄₀N₂
• 分子量: 740.947
• InChiKey: ZTPLLSPYFNCCEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.8
• 重原子数：
  58
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-溴三苯胺 在 四(三苯基膦)钯 、 正丁基锂 、 sodium carbonate 作用下， 以 四氢呋喃 、 乙醇 、 甲苯 为溶剂， 反应 22.0h， 生成 4,4'-bis[4-(diphenylamino)phenyl]-1,1'-binaphthyl
  参考文献：
  名称：

  稳定，玻璃状和多功能的双萘衍生物，能够有效地传输空穴，形成宿主并发出深蓝光

  摘要：

  有机发光二极管（OLED）在显示器和固态照明中具有巨大的潜在应用。稳定性，成本和蓝色发射是支配OLED未来的关键问题。报道了一系列的三种联萘（BN）衍生物的合成和光电学。BN 1-3是“无熔点”且高度稳定的材料，可形成非常好的无定形玻璃状薄膜。它们在高达485–545°C的温度下分解。在25 mA cm -2的恒定电流密度下，ITO / BN 3 / Al单层器件的寿命（> 80 h）比ITO / NPB / Al单层器件（8 h）长得多）。另外，基于BN 1的多层器件的寿命比基于NPB的类似设备更长。BN是高效且用途广泛的OLED材料：它们可用作空穴传输层（HTL），主体和深蓝色发光材料。这种多功能性可以降低大规模材料制造的成本。更重要的是，深蓝色电致发光（在444 nm处具有CIE坐标（0.16，0.11）的发射峰，在0.21 mA cm -2处为3.23 cd A -1，在9 V时为25200

  DOI：

  10.1002/adfm.201000299

文献信息

• ORGANIC ELECTROLUMESCENCE DEVICE
  申请人：Hosokawa Chishio

  公开号：US20070142671A1

  公开（公告）日：2007-06-21

  Materials for organic electroluminescence devices are represented by following general formula [1]: wherein A represents a chrysene group, X 1 to X 4 each independently represent a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, X 1 and X 2 may be bonded to each other, X 3 and X 4 may be bonded to each other, Y 1 to Y 4 each independently represent an organic group represented by general formula [2], a to d each represent an integer of 0 to 2 and, a+b+c+d≧0; general formula [2] being: wherein R 1 to R 4 each independently represent hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, cyano group or form a triple bond by a linkage of R 1 and R 2 or R 3 and R 4 , Z represents a substituted or unsubstituted aryl group having 6 to 20 carbon atoms and n represents 0 or 1.
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Hosokawa Chishio

  公开号：US20120153815A1

  公开（公告）日：2012-06-21

  A material for an organic electroluminescence device having the formula: wherein Ar 1 and Ar 3 each independently represent a substituted or unsubstituted phenylene group, X 5 represents a substituted or unsubstituted naphthyl group or a substituted or unsubstituted phenanthryl group, X 6 represents a substituted or unsubstituted phenyl group, and X 7 and X 8 each independently represent a substituted or unsubstituted biphenyl group or a substituted or unsubstituted terphenyl group. An organic electroluminescence device having (i) a light emitting layer, or (ii) a plurality of thin films of organic compounds having a light emitting layer, disposed between a pair of electrodes, wherein at least one of the thin films of organic compounds is a layer containing the material having the formula above.
• [EN] 1,1'-BINAPHTHYL-4,4'-DIAMINE DERIVATIVES FOR LUMINESCENCE OF ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THEM<br/>[FR] DÉRIVÉS DE 1,1'-BINAPHTYL-4,4'-DIAMINE POUR LA LUMINESCENCE D'UN DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES UTILISANT
  申请人：SAMYANGEMS CO LTD

  公开号：WO2013070026A1

  公开（公告）日：2013-05-16

  The present invention relates to binaphthyl amine derivatives suitable for use in light sources of displays such as mobile phones, navigation systems, TV sets, etc., and more particularly to a 1,1'-binaphthyl-4,4'-diamine derivative for luminescence of an organic electroluminescent device.
• Stable, Glassy, and Versatile Binaphthalene Derivatives Capable of Efficient Hole Transport, Hosting, and Deep-Blue Light Emission
  作者：Bin Wei、Ji-Zhong Liu、Yong Zhang、Jian-Hua Zhang、Hua-Nan Peng、He-Liang Fan、Yan-Bo He、Xi-Cun Gao

  DOI：10.1002/adfm.201000299

  日期：——

  based on BN1 is longer than a similar device based on NPB. BNs are efficient and versatile OLED materials: they can be used as a hole‐transport layer (HTL), a host, and a deep‐blue‐light‐emitting material. This versatility may cut the cost of large‐scale material manufacture. More importantly, the deep‐blue electroluminescence (emission peak at 444 nm with CIE coordinates (0.16, 0.11), 3.23 cd A−1 at

  有机发光二极管（OLED）在显示器和固态照明中具有巨大的潜在应用。稳定性，成本和蓝色发射是支配OLED未来的关键问题。报道了一系列的三种联萘（BN）衍生物的合成和光电学。BN 1-3是“无熔点”且高度稳定的材料，可形成非常好的无定形玻璃状薄膜。它们在高达485–545°C的温度下分解。在25 mA cm -2的恒定电流密度下，ITO / BN 3 / Al单层器件的寿命（> 80 h）比ITO / NPB / Al单层器件（8 h）长得多）。另外，基于BN 1的多层器件的寿命比基于NPB的类似设备更长。BN是高效且用途广泛的OLED材料：它们可用作空穴传输层（HTL），主体和深蓝色发光材料。这种多功能性可以降低大规模材料制造的成本。更重要的是，深蓝色电致发光（在444 nm处具有CIE坐标（0.16，0.11）的发射峰，在0.21 mA cm -2处为3.23 cd A -1，在9 V时为25200