(η5-cyclopentadienyl)[η6-[N-(trifluoroacetoxymercurio)]aniline]iron(II) hexafluorophosphate(V) | 726191-50-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (η5-cyclopentadienyl)[η6-[N-(trifluoroacetoxymercurio)]aniline]iron(II) hexafluorophosphate(V)
• 英文别名: anilinomercury(1+);cyclopenta-1,3-diene;iron(2+);2,2,2-trifluoroacetate;hexafluorophosphate
• CAS: 726191-50-0
• 化学式: C₁₃H₁₁F₃FeHgNO₂*F₆P
• 分子量: 671.632
• InChiKey: BHJXEDZQYBGTGH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-cyclopentadienyl)[η6-[N-(trifluoroacetoxymercurio)]aniline]iron(II) hexafluorophosphate(V) 、 calcium chloride 以 further solvent(s) 为溶剂， 以70%的产率得到(η5-cyclopentadienyl)[η6-N-(chloromercurio)aniline]iron(II) hexafluorophosphate(V)
  参考文献：
  名称：

  Mercuration with Mercury(II) Trifluoroacetate of ( ⁶-Aniline)- or (N,N-dimethylaniline)( ⁵-cyclopentadienyl)iron(II)

  摘要：

  The reaction of mercury(II) trifluoroacetate with the hexafluorophosphate of the eta(6)-aniline-eta(5)-cyclopentadienyliron(II) cation under reflux in dry ethanol gives rise to N-mono- and N,N-disubstituted mercury-containing salts of this cation. The same mercury-containing salts have been synthesized by the action of mercury(II) trifluoroacetate on the deprotonation product of the (eta(6)-aniline)(eta(5)-cyclopentadienyl)-iron(II) cation. Direct mercuration of the [eta(6)-(N,N-dimethylaniline)](eta(5)-cyclopentadienyl)iron(II) cation into the para position of the benzene ring of the arene ligand has been performed. The reactivity of the compounds obtained has been studied.

  DOI：

  10.1023/b:rugc.0000016012.56251.ef
• 作为产物：
  描述：

  (amine-η6-benzene)(η5-cyclopentadienyl)iron(II) hexafluorophosphate 、 mercury(II) trifluoroacetate 在 potassium tert-butylate 作用下， 以 further solvent(s) 为溶剂， 生成 (η5-cyclopentadienyl)[η6-[N-(trifluoroacetoxymercurio)]aniline]iron(II) hexafluorophosphate(V)
  参考文献：
  名称：

  Mercuration with Mercury(II) Trifluoroacetate of ( ⁶-Aniline)- or (N,N-dimethylaniline)( ⁵-cyclopentadienyl)iron(II)

  摘要：

  The reaction of mercury(II) trifluoroacetate with the hexafluorophosphate of the eta(6)-aniline-eta(5)-cyclopentadienyliron(II) cation under reflux in dry ethanol gives rise to N-mono- and N,N-disubstituted mercury-containing salts of this cation. The same mercury-containing salts have been synthesized by the action of mercury(II) trifluoroacetate on the deprotonation product of the (eta(6)-aniline)(eta(5)-cyclopentadienyl)-iron(II) cation. Direct mercuration of the [eta(6)-(N,N-dimethylaniline)](eta(5)-cyclopentadienyl)iron(II) cation into the para position of the benzene ring of the arene ligand has been performed. The reactivity of the compounds obtained has been studied.

  DOI：

  10.1023/b:rugc.0000016012.56251.ef