Mo(dimethylamido)2(N(CH2C4H2N(3,5-C6H3(CF3)2))2(CH2C4H3N(3,5-C6H3(CF3)2))) | 955934-89-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: Mo(dimethylamido)2(N(CH2C4H2N(3,5-C6H3(CF3)2))2(CH2C4H3N(3,5-C6H3(CF3)2)))
• CAS: 955934-89-1
• 化学式: C₄₃H₃₄F₁₈MoN₆
• 分子量: 1072.69
• InChiKey: NMFFRMVCVUDIFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N(CH2C4H3N(3,5-C6H3(CF3)2))3 、 (T-4)-四(N-甲基甲氨基)-钼 以 正戊烷 为溶剂， 生成 Mo(dimethylamido)2(N(CH2C4H2N(3,5-C6H3(CF3)2))2(CH2C4H3N(3,5-C6H3(CF3)2)))
  参考文献：
  名称：

  Tris(pyrrolyl-α-methyl)amines that Sterically Protect a Trigonal Metal Site

  摘要：

  Three substituted tris(pyrrolyl-alpha-methyl)amines (H-3[Aryl(3)TPA]) (Aryl = 2,4,6-C6H2Me3, 2,4,6-C6H2(i7Pr)(3) (Trip), or 3,5-C6H3(CF3)(2)) have been prepared. An X-ray study of [TriP(3)TPA]MoCl shows it to be a distorted trigonal bipyramidal species in which the 2,4,6-triisopropylphenyl substituents surround and protect the apical chloride. Attempts to prepare other Mo, Zr, and Hf complexes yielded species in which one pyrrole-containing arm remained free (Mo) or dimethylamine remained in the coordination sphere of [Aryl(3)TPA](3-) complexes (Zr, Hf).

  DOI：

  10.1021/ic701472y