Λ-Na[Co(acac)2(ox)] | 15711-29-2

• 分子结构分类: 有机化合物
• 英文名称: Λ-Na[Co(acac)2(ox)]
• CAS: 15711-29-2
• 化学式: C₁₂H₁₄CoO₈*Na
• 分子量: 368.221
• InChiKey: KZXRGDNBGINRQT-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  ytterbium(III) chloride hexahydrate 、 Λ-Na[Co(acac)2(ox)] 、 三吡唑啉基硼氢钾 以 水 为溶剂， 生成 Yb(hydridotris(1-pyrazolyl)borato)₃ 、 (Λ-Δ)-[Co(acac)2(ox)Yb(BHpz3)2]
  参考文献：
  名称：

  Heterobimetallic (acac)2Co(ox)Ln(HBpz3)2 complexes: synthesis, characterization and spectroscopic properties

  摘要：

  The syntheses and characterizations of a series of complexes, [(acac)(2)Co(ox)Ln(HBpz(3))(2)] (Co(ox)Ln, Ln = Sm to Lu) is reported here. Cobalt(III) complexes, Co(ox)Ln, have been compared with chromium(III) complexes, Cr(ox)Ln due to their analogous features in view of structure and spectroscopy. NIR CD spectrum of [(acac)(2)Co(ox)Yb(HBpz(3))(2)] is examined in comparison with that of the related complexes to reveal the stereospecific formation with configurational chirality around Yb-III ion. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00328-1