Dimethyl 3,3'-<<2,2,2-trifluoro-1-(trifluoromethyl)ethylidene>bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetafluoropropionate) | 131043-09-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Dimethyl 3,3'-<<2,2,2-trifluoro-1-(trifluoromethyl)ethylidene>bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetafluoropropionate)
• 英文别名: methyl 2,2,3,3-tetrafluoro-3-[4-[1,1,1,3,3,3-hexafluoro-2-[4-(1,1,2,2-tetrafluoro-3-methoxy-3-oxopropoxy)phenyl]propan-2-yl]phenoxy]propanoate
• CAS: 131043-09-9
• 化学式: C₂₃H₁₄F₁₄O₆
• 分子量: 652.338
• InChiKey: WHYXWBIJLMOAGF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  43
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为反应物：
  描述：

  Dimethyl 3,3'-<<2,2,2-trifluoro-1-(trifluoromethyl)ethylidene>bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetafluoropropionate) 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 以87%的产率得到3,3'-<<2,2,2-Trifluoro-1-(trifluoromethyl)ethylidene>bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetafluoropropanol)
  参考文献：
  名称：

  Fluorinated bifunctional derivatives of bisphenol A

  摘要：

  Bisphenol A reacted as its disodium salt with tetrafluoroethylene and carbon dioxide followed by dimethyl sulfate to give in high yield a symmetrical dimethyl ester assembled from seven structural elements. This diester was transformed into the corresponding diol, diamide, diamine, diisocyanate, and bis(methyl carbamate). Analogous diesters were prepared by using bisphenol A and chlorotrifluoroethylene as well as hexafluorobisphenol A and tetrafluoroethylene. Both of these esters were transformed into other bifunctional derivatives. Catalytic hydrogenation of the diol derived from bisphenol A and tetrafluoroethylene was accompanied by hydrogenolysis of the aryl-oxygen bonds.

  DOI：

  10.1021/jo00001a030
• 作为产物：
  描述：

  四氟乙烯 、 二氧化碳 、 disodium,4-[1,1,1,3,3,3-hexafluoro-2-(4-oxidophenyl)propan-2-yl]phenolate 、 硫酸二甲酯 生成 2,2,3,3-Tetrafluoro-3-(4-{2,2,2-trifluoro-1-[4-(1,1,2,2-tetrafluoro-ethoxy)-phenyl]-1-trifluoromethyl-ethyl}-phenoxy)-propionic acid methyl ester 、 Dimethyl 3,3'-<<2,2,2-trifluoro-1-(trifluoromethyl)ethylidene>bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetafluoropropionate)
  参考文献：
  名称：

  Fluorinated bifunctional derivatives of bisphenol A

  摘要：

  Bisphenol A reacted as its disodium salt with tetrafluoroethylene and carbon dioxide followed by dimethyl sulfate to give in high yield a symmetrical dimethyl ester assembled from seven structural elements. This diester was transformed into the corresponding diol, diamide, diamine, diisocyanate, and bis(methyl carbamate). Analogous diesters were prepared by using bisphenol A and chlorotrifluoroethylene as well as hexafluorobisphenol A and tetrafluoroethylene. Both of these esters were transformed into other bifunctional derivatives. Catalytic hydrogenation of the diol derived from bisphenol A and tetrafluoroethylene was accompanied by hydrogenolysis of the aryl-oxygen bonds.

  DOI：

  10.1021/jo00001a030

文献信息

• ARNOLD-STANTON, REGINA;LEMAL, DAVID M., J. ORG. CHEM., 56,(1991) N, C. 146-151
  作者：ARNOLD-STANTON, REGINA、LEMAL, DAVID M.

  DOI：——

  日期：——