[methyl(phenyl)phosphoryl]benzene;thulium(3+);hexafluorophosphate;dinitrate | 364048-59-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [methyl(phenyl)phosphoryl]benzene;thulium(3+);hexafluorophosphate;dinitrate
• CAS: 364048-59-9
• 化学式: C₅₂H₅₂N₂O₁₀P₄Tm*F₆P
• 分子量: 1302.79
• InChiKey: OTKHXXZEWCBXNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 甲基二苯基氧化膦 、 thulium(III) nitrate hydrate 以 丙酮 为溶剂， 以55%的产率得到[methyl(phenyl)phosphoryl]benzene;thulium(3+);hexafluorophosphate;dinitrate
  参考文献：
  名称：

  Lanthanide nitrate complexes of diphenylmethylphosphine oxide: synthesis and spectroscopic studies. Crystal structures of [La(Ph2MePO)3(NO3)3], [La(Ph2MePO)4(NO3)3]·xMe2CO and [Yb(Ph2MePO)4(NO3)2]PF6

  摘要：

  The reaction of Ln(NO3)(3). 6H(2)O (Ln = lanthanide except Pm) with Ph2MePO in a 1:3 or 1:4 ratio in acetone or ethanol produces [Ln(Ph2MePO)(3)(NO3)(3)] which have been characterised by analysis, IR, H-1 and P-31{H-1} NR IR spectroscopy and conductance measurements. The [Ln'(Ph2MePO)(3)(NO3)(3)] (Ln' = Pr-Tb) exist only as tris complexes in solution and are unaffected by the presence of excess Ph2MePO. In contrast the [Ln"(Ph2MePO)(3)(NO3)(3)] (Ln" = Ho-Lu) partially decompose in CH2Cl2 solution into [Ln"(Ph2MePO)(4)(NO3)(2)](+), and [Ln"(Ph2MePO)(4)(NO3)(2)]PF6 are readily isolated from Ln"(NO3)(3), Ph2MePO and NH4PF6 in acetone. For lanthanum only, a neutral 1:4 complex [La(Ph2MePO)(4)(NO3)(3)] was isolated. X-ray crystal structures show that [La(Ph2MePO)(3)(NO3)(3)] contains nine-coordinate La, whilst [La(Ph2MePO)(4)(NO3)(3)]. xMe(2)CO contains a ten-coordinate metal centre. The structure of [Yb(Ph2MePO)(4)(NO3)(2)]PF6 reveals an eight-coordinate cation and all complexes contain bidentate nitrate-groups. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00796-3