2,4:5',3'':4'':2'''-quaterpyridine | 845513-26-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,4:5',3'':4'':2'''-quaterpyridine
• 英文别名: qtbpy；4-Pyridin-2-yl-3-(4-pyridin-2-ylpyridin-3-yl)pyridine
• CAS: 845513-26-0
• 化学式: C₂₀H₁₄N₄
• 分子量: 310.358
• InChiKey: HUOAESJNOGWMHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  molybdenum(VI) oxide 、 arsenic(V) oxide 、 copper(II) acetate monohydrate 、 2,4:5',3'':4'':2'''-quaterpyridine 在 HF 作用下， 以 水 为溶剂， 以30%的产率得到[(Cu3(qtpyr)2)Mo12O36(AsO4)]*0.40H2O
  参考文献：
  名称：

  Organic–inorganic hybrid materials constructed from copper-organoimine subunits and molybdoarsonate clusters

  摘要：

  The hydrothermal reactions of MoO3, As2O5, Cu(CH3CO2)(2) . H2O and an appropriate organonitrogen ligand in the presence of HF as mineralizer yield a series of bimetallic oxides of the Cu/Mo/O/As system. The compounds [{Cu,(4,7-phen)(4,7-phenH)(2)}-Mo12AsO40] . 2.66H(2)O (1 . 2.66H(2)O) and [{Cu-3(qtpyr)(2)}Mo12AsO40] . 0.4H(2)O (2 . 0.4H(2)O) (qtpyr = 2,4':5',3",4",2'''-quaterpyridine) are two-dimensional phases constructed from Keggin clusters linked through binuclear {Cu,(4,7-phen)(4,7-Hphen)(2)}(2+) units in 1 and {Cu-3(qtpyr)(2)}(n)(3n+) metal organic networks in 2. In contrast, the structure of [{Cu-2(2,4'-Hbpy)(4)}Mo18As2O62] . 2H(2)O (3 . 2H(2)O) is one-dimensional, consisting of Dawson clusters linked through binuclear {Cu-2(Hbpy)(4)}(6+) subunits. In the case of the compounds [{Cu(5,5'-dimethyl-2,2'-bpy)}(2)Mo2O4F2(AsO4)(2)](4) and [{Cu(phen)}(2)Mo2O4F2(AsO4)(2)] (5), the fluoride mineralizer has been incorporated into the structure to give one-dimensional phases constructed from oxyfluoride {Mo2O4F2(AsO4)(2)}(2-) clusters bridged through {Cu(organonitrogen)}(2+) units. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.004