9,9-dichloro-1-phenylthio <6.1.0> bicyclononane | 143741-58-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 9,9-dichloro-1-phenylthio <6.1.0> bicyclononane
• 英文别名: 9,9-Dichloro-1-phenylsulfanylbicyclo[6.1.0]nonane
• CAS: 143741-58-6
• 化学式: C₁₅H₁₈Cl₂S
• 分子量: 301.28
• InChiKey: UTMMMEHXONYHGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9,9-dichloro-1-phenylthio <6.1.0> bicyclononane 在 aluminum oxide 、 silver tetrafluoroborate 作用下， 反应 0.25h， 以62%的产率得到2-phenylthio-3-chloro-1,3-cyclononadiene
  参考文献：
  名称：

  Dihalocyclopropanation of Phenylthio or Butylthiocycloalkenes Under Phase Transfer Conditions. Opening of Cyclopropanes Under Microwave Irradiation

  摘要：

  Dihalocarbenes (X=Cl,Br) generated under phase transfer conditions added to phenylthio or butylthiocylcloalkenes give corresponding 1,1-dihalo-2-thiobutyl or thiophenyl-cyclopropanes. The ring opening of dichlorophenylthiocyclopropanes (2a, 2b, 2c) was obtained by using silver tetrafluoborate on alumina under microwave irradiation.

  DOI：

  10.1080/00397919208021338
• 作为产物：
  描述：

  氯仿 、 1-phenylthio-1-cyclooctene 在 sodium hydroxide 、 苄基三乙基氯化铵 作用下， 反应 0.25h， 以93%的产率得到9,9-dichloro-1-phenylthio <6.1.0> bicyclononane
  参考文献：
  名称：

  Dihalocyclopropanation of Phenylthio or Butylthiocycloalkenes Under Phase Transfer Conditions. Opening of Cyclopropanes Under Microwave Irradiation

  摘要：

  Dihalocarbenes (X=Cl,Br) generated under phase transfer conditions added to phenylthio or butylthiocylcloalkenes give corresponding 1,1-dihalo-2-thiobutyl or thiophenyl-cyclopropanes. The ring opening of dichlorophenylthiocyclopropanes (2a, 2b, 2c) was obtained by using silver tetrafluoborate on alumina under microwave irradiation.

  DOI：

  10.1080/00397919208021338

文献信息

• Dihalocyclopropanation of Phenylthio or Butylthiocycloalkenes Under Phase Transfer Conditions. Opening of Cyclopropanes Under Microwave Irradiation
  作者：Didier Villemin、Bouchta Labiad

  DOI：10.1080/00397919208021338

  日期：1992.7

  Dihalocarbenes (X=Cl,Br) generated under phase transfer conditions added to phenylthio or butylthiocylcloalkenes give corresponding 1,1-dihalo-2-thiobutyl or thiophenyl-cyclopropanes. The ring opening of dichlorophenylthiocyclopropanes (2a, 2b, 2c) was obtained by using silver tetrafluoborate on alumina under microwave irradiation.