| 590423-60-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• CAS: 590423-60-2
• 化学式: C₁₂H₆Cu₂N₄O₆S₈
• 分子量: 685.823
• InChiKey: GCVJTYUJSWRPIA-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [C₄H₂N₂(O)3(CS₂)2]^(2-)*2Na⁽¹⁺⁾=Na₂[C₄H₂N₂(O)3(CS₂)2] 、 copper dichloride 以 甲醇 为溶剂， 以51%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of 2,4,6‐Pyrimidinetrione Dithiocarbamate Complexes and 2,4,6‐Pyrimidinetrione Dithiocarbamate Macrocyclic Complexes

  摘要：

  The sodium salts of pyrimidinetrione dithiocarbamate (NaL1) and pyrimidinetrione dithiocarbamate (Na2L2) and their first row-transition metal complexes of the type [M(L-1)(2)], [M'(L-1)(3)] and [M-2(L-2)(2)], where M=Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and M'=Cr(III), Fe(III) have been synthesized and characterized. Spectroscopic studies suggest that the interaction of L-2 with a divalent metal ion forms binuclear dithiocarbamate macrocyclic complexes. Conductivity measurements reveal that all of the complexes are non-electrolytes. The magnetic moment values and electronic spectra suggest that the Mn(II) and Co(II) complexes are tetrahedral, the Ni(II) and Cu(II) complexes are square-planar while the Fe(III) and Cr(III) complexes are proposed to have an octahedral structure.

  DOI：

  10.1081/sim-120020324