N'-benzoyl-N-tert-butyl-4-iodobenzohydrazide | 112427-73-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N'-benzoyl-N-tert-butyl-4-iodobenzohydrazide
• CAS: 112427-73-3
• 化学式: C₁₈H₁₉IN₂O₂
• 分子量: 422.266
• InChiKey: HPEOMOXKNKVTAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  49.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N'-tert-butyl-N-benzoylhydrazine 、 4-碘苯甲酰氯 在 sodium hydroxide 作用下， 以 乙醚 为溶剂， 反应 3.0h， 生成 N'-benzoyl-N-tert-butyl-4-iodobenzohydrazide
  参考文献：
  名称：

  Quantitative structure-activity analysis of larvicidal 1-(substituted benzoyl)-2-benzoyl-1-tert-butylhydrazines againstChilo suppressalis

  摘要：

  AbstractThe larvicidal activity of a number of 1‐(substituted benzoyl)‐2‐benzoyl–1 ‐ten‐butylhydrazines against the rice stem borer (Chilo suppressalis Walk.) was measured. Variations in the activity were examined quantitatively using physico‐chemical substituent and molecular parameters and regression analysis. The results indicated that the molecular hydrophobicity and the electron‐withdrawing inductive/ field effect of ontho substituents are favourable to larvicidal activity. The bulkiness of substituents at the meta and para positions was unfavourable to activity, substitution at the para position being more unfavourable than that at the meta position in terms of van der Waals' volume. The 2,3–, 2,5‐ and 2,6‐disubstitution patterns were also unfavourable to activity. Reductions in larvicidal activity caused by the 2,6‐,‐ 2,3,5‐ and 2,3,4,5‐substitutions were greater than those induced by the 2,3‐ and 2,5‐disubstitutions. When the sum of contributions from favourable effects is greater than that from unfavourable effects, the larvicidal activity is expected to be superior to that of the unsubstituted compound.

  DOI：

  10.1002/ps.2780410210

文献信息

• Insecticidal N'-substituted-N,N'-diacylhydrazines
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0236618A2

  公开（公告）日：1987-09-16

  This invention is concerned with insecticidal compositions containing N'-substituted-N,N'-diacylhydrazines, methods of using such compositions and with certain of the insecticidal N'-substituted-N,N'-diacylhydrazines which are novel compounds.

  本发明涉及含有 N'-取代-N,N'-二乙酰肼的杀虫组合物、使用此类组合物的方法以及某些杀虫 N'-取代-N,N'-二乙酰肼的新型化合物。
• Compositions comprising arylcyclobutene and polymeric compositions prepared therefrom
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0242033A2

  公开（公告）日：1987-10-21

  A monomer comprises a reactive arylcyclobutene moiety and a molecular group which is bonded to the aryl group of the arylcyclobutene moiety. The molecular group can comprise an organic molecular group, especially at least one unsaturated alkyl group, ie. a group of two aliphatic or alicyclic carbon atoms bonded by a double or a triple bond, or an inorganic molecular group. Suitable organic molecular groups include aliphatic, cyloaliphatic, heterocyclic and aromatic moieities. Polymers are prepared by reacting the monomeric compounds of the invention under polymerization conditions, optionally in the presence of copolymerizable monomers.

  单体包括一个活性芳基环丁烯分子和一个与芳基环丁烯分子的芳基键合的分子基团。分子基团可以是有机分子基团，特别是至少一个不饱和烷基，即由两个脂肪族或脂环族碳原子通过双键或三键结合而成的基团，也可以是无机分子基团。合适的有机分子基团包括脂肪族、脂环族、杂环族和芳香族。在聚合条件下，可选择在可共聚单体存在的情况下，使本发明的单体化合物发生反应，制备聚合物。
• [EN] COMPOSITIONS COMPRISING ARYLCYCLOBUTENE AND POLYMERIC COMPOSITIONS PREPARED THEREFROM
  申请人：THE DOW CHEMICAL COMPANY

  公开号：WO1987005303A1

  公开（公告）日：1987-09-11

  (EN) Monomeric compound comprising (a) a reactive arylcyclobutene moiety and (b) a molecular group which is bonded to the aryl group of the arylcyclobutene moiety. The molecular group which is bonded to the aryl moiety can comprise at least one unsaturated alkyl group, i.e., a group of two aliphatic or alicyclic carbon atoms bonded by a double or a triple bond. The molecular group can also comprise an organic molecular group or an inorganic molecular group. Suitable organic molecular groups are aliphatic, cycloaliphatic, heterocyclic and aromatic moieties. The invention also concerns polymeric compositions prepared by reacting the monomeric compounds of the invention under polymerization conditions.(FR) Un composé monomère comprend (a) une fraction d'arylcyclobutène réactive et (b) un groupe moléculaire lié au groupe aryle de la fraction d'arylcyclobutène. Le groupe moléculaire lié à la fraction aryle peut comprendre au moins un groupe aryle non saturé, soit un groupe de deux atomes de carbone aliphatiques ou alicycliques liés par une liaison double ou triple. Le groupe moléculaire peut également comprendre un groupe moléculaire organique ou un groupe moléculaire inorganique. Les groupes moléculaires organiques appropriés sont des fractions aliphatiques, cycloaliphatiques, hétérocycliques et aromatiques. Des compositions polymères préparées par réaction des composés monomères de la présente invention dans des conditions de polymérisation sont également décrites.