N,N-bis(diphenylphosphanylmethyl)-amino-thiocarbamide | 1333524-98-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-bis(diphenylphosphanylmethyl)-amino-thiocarbamide
• 英文别名: [bis(diphenylphosphanylmethyl)amino]thiourea
• CAS: 1333524-98-3
• 化学式: C₂₇H₂₇N₃P₂S
• 分子量: 487.545
• InChiKey: CIAMADITWPAXFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  33
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  73.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N-bis(diphenylphosphanylmethyl)-amino-thiocarbamide 、 alkaline earth salt of/the/ methylsulfuric acid 以 水 、 乙腈 为溶剂， 反应 24.0h， 以31%的产率得到[Au2((diphenylphosphino)methanethiol)2]n
  参考文献：
  名称：

  一种具有催化光降解污染物性质的金配合物及 其制备方法和应用

  摘要：

  本发明公开了一种具有催化光降解污染物性质的金配合物及其制备方法和应用。具体而言，本发明的金配合物可以通过下列方法制备获得：将四水合氯金酸、N,N-二(二苯基膦甲基)-氨基-硫脲与乙腈和水的混合溶剂加入到硬质玻璃管中并封管，随后将玻璃管放入烘箱中反应，反应完成后以5～10℃·h-1的速率使玻璃管缓慢降温，温度降至室温后，即得到目标产物。本发明公开的金配合物在用于催化光降解硝基类、偶氮类污染物的反应中具有较高的光反应催化活性，可以多次循环利用，使废水中的硝基类以及偶氮类污染物基本完全降解。

  公开号：

  CN103980299B
• 作为产物：
  描述：

  聚合甲醛 、 氨基硫脲 、 二苯基膦 以 甲醇 为溶剂， 反应 1.5h， 以97%的产率得到N,N-bis(diphenylphosphanylmethyl)-amino-thiocarbamide
  参考文献：
  名称：

  One cationic dinuclear silver(I) complex of dppatc formed in situ by replacing ethylenediamine units of dppeda through aminothiocarbamide

  摘要：

  Reaction of silver nitrate with N,N,N',N'-tetra(diphenylphosphanylmethyl)ethylenediamine (dppeda) in the presence of aminothiocarbamide in CH2Cl2/MeOH afforded an unexpected and low-yield binuclear complex [Ag-2(dppatc)(2)](NO3)(2)center dot 2MeOH (dppatc = N,N-bis( diphenylphosphanylmethyl)aminothiocarbamide) (1). An X-ray analysis revealed that the [Ag-2(dppatc)(2)](2+) dication of 1 contains a centrosymmetric double half-open cage structure in which two Ag centers are bridged by a pair of the heteroscopionate dppatc ligands via four Ag-mu-S and four Ag-P bonds. The in situ-formed dppatc ligand in 1 could be readily generated by one-pot and high-yield reaction of diphenylphosphine with formaldehyde and aminothiocarbamide. Further reaction of AgNO3 with dppatc could produce 1 in a relatively high yield. The results provided an efficient route to the synthesis of dppatc and also an interesting insight into its coordination chemistry. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.07.002

文献信息

• Syntheses and structures of two gold(<scp>i</scp>) coordination compounds derived from P–S hybrid ligands and their efficient catalytic performance in the photodegradation of nitroaromatics in water
  作者：Hai-Xiao Qi、Jian-Feng Wang、Zhi-Gang Ren、Jin-Jiao Ning、Jian-Ping Lang

  DOI：10.1039/c5dt00167f

  日期：——

  Two Au–P–S complexes [Au₂(dppatc)₂]Cl₂ and [Au(dppmt)]₂ were prepared and they showed high catalytic activity toward the photodegradation of nitroaromatics in water.

  两个Au-P-S复合物[Au2(dppatc)2]Cl2和[Au(dppmt)]2已经制备，它们在水中对硝基芳烃的光降解表现出高催化活性。
• One cationic dinuclear silver(I) complex of dppatc formed in situ by replacing ethylenediamine units of dppeda through aminothiocarbamide
  作者：Duan-Xiu Li、Zhi-Gang Ren、Hui-Fang Wang、Jian-Ping Lang

  DOI：10.1016/j.inoche.2011.07.002

  日期：2011.10

  Reaction of silver nitrate with N,N,N',N'-tetra(diphenylphosphanylmethyl)ethylenediamine (dppeda) in the presence of aminothiocarbamide in CH2Cl2/MeOH afforded an unexpected and low-yield binuclear complex [Ag-2(dppatc)(2)](NO3)(2)center dot 2MeOH (dppatc = N,N-bis( diphenylphosphanylmethyl)aminothiocarbamide) (1). An X-ray analysis revealed that the [Ag-2(dppatc)(2)](2+) dication of 1 contains a centrosymmetric double half-open cage structure in which two Ag centers are bridged by a pair of the heteroscopionate dppatc ligands via four Ag-mu-S and four Ag-P bonds. The in situ-formed dppatc ligand in 1 could be readily generated by one-pot and high-yield reaction of diphenylphosphine with formaldehyde and aminothiocarbamide. Further reaction of AgNO3 with dppatc could produce 1 in a relatively high yield. The results provided an efficient route to the synthesis of dppatc and also an interesting insight into its coordination chemistry. (C) 2011 Elsevier B.V. All rights reserved.
• 一种具有催化光降解污染物性质的金配合物及 其制备方法和应用
  申请人：苏州大学

  公开号：CN103980299B

  公开（公告）日：2016-03-02

  本发明公开了一种具有催化光降解污染物性质的金配合物及其制备方法和应用。具体而言，本发明的金配合物可以通过下列方法制备获得：将四水合氯金酸、N,N-二(二苯基膦甲基)-氨基-硫脲与乙腈和水的混合溶剂加入到硬质玻璃管中并封管，随后将玻璃管放入烘箱中反应，反应完成后以5～10℃·h-1的速率使玻璃管缓慢降温，温度降至室温后，即得到目标产物。本发明公开的金配合物在用于催化光降解硝基类、偶氮类污染物的反应中具有较高的光反应催化活性，可以多次循环利用，使废水中的硝基类以及偶氮类污染物基本完全降解。