anthra<2,3-b>thiophene | 227-56-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: anthra<2,3-b>thiophene
• 英文别名: anthra[2,1-b]thiophene；ANTHRA(2,1-b)THIOPHENE；naphtho[2,3-e][1]benzothiole
• CAS: 227-56-5
• 化学式: C₁₆H₁₀S
• 分子量: 234.321
• InChiKey: PAYSBLPSJQBEJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,4-萘醌 在 lithium aluminium tetrahydride 、 三氯化铝 、 四氯苯醌 作用下， 以 乙醚 、 甲苯 为溶剂， 反应 65.0h， 生成 anthra<2,3-b>thiophene
  参考文献：
  名称：

  Tominaga, Yoshinori; Lee, Milton L.; Castle, Raymond N., Journal of Heterocyclic Chemistry, 1981, vol. 18, p. 967 - 972

  摘要：

  DOI：

文献信息

• [EN] ANTHRADITHIOPHENE DERIVATIVES, PROCESS FOR THE PREPARATION THEREOF AND POLYMERS THAT CONTAIN THEM<br/>[FR] DÉRIVÉS D'ANTHRADITHIOPHÈNE, PROCÉDÉ DE PRÉPARATION ASSOCIÉ ET POLYMÈRES LES CONTENANT
  申请人：ENI SPA

  公开号：WO2019175367A1

  公开（公告）日：2019-09-19

  Anthradithiophene derivative having general formula (I). Said anthradithiophene derivative can be advantageously used in the synthesis of electron donor polymers, said polymers being further subject matter of the present invention. Said polymers can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support or on a flexible support. Furthermore, said polymers can be advantageously used in the construction of Organic Thin Film Transistors (OTFTs), or Organic Field Effect Transistors (OFETs), or Organic Light-Emitting Diodes (OLEDs).

  具有通式（I）的蒽二噻吩衍生物。该蒽二噻吩衍生物可以优势地用于电子给体聚合物的合成，该聚合物是本发明的进一步主题。该聚合物可以优势地用于光伏器件（或太阳能器件）的构建，例如光伏电池（或太阳能电池）、光伏模块（或太阳能模块），无论是在刚性支撑上还是在柔性支撑上。此外，该聚合物可以优势地用于有机薄膜晶体管（OTFT）或有机场效应晶体管（OFET）或有机发光二极管（OLED）的构建。
• Polycyclic thiophene lubricating oil additive
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0250273A2

  公开（公告）日：1987-12-23

  Inexpensive lubricating oil antioxidants having a solubilizing group which comprises alkyl and cycloalkyl-substituted aromatics and a reducing thiophenyl group, which are useful motor oil additives. Method of reducing coking tendencies of lubricating oils by incorporating the substituted aromatic antioxidants.

  价格低廉的润滑油抗氧化剂，其增溶基团包括烷基和环烷基取代芳香族和还原噻吩基团，是有用的机油添加剂。 通过加入取代芳香族抗氧化剂降低润滑油结焦倾向的方法。
• TOMINAGA, YOSHINORI;LEE, M. L.;CASTLE, R. N., J. HETEROCYCL. CHEM., 1981, 18, N 5, 967-972
  作者：TOMINAGA, YOSHINORI、LEE, M. L.、CASTLE, R. N.

  DOI：——

  日期：——
• ANTHRADITHIOPHENE DERIVATIVES, PROCESS FOR THE PREPARATION THEREOF AND POLYMERS THAT CONTAIN THEM
  申请人：ENI S.p.A.

  公开号：EP3765463A1

  公开（公告）日：2021-01-20
• POLYMERIC PHOTOVOLTAIC CELL WITH INVERTED STRUCTURE COMPRISING A CONJUGATED POLYMER COMPRISING AN ANTHRADITHIOPHENE DERIVATIVE
  申请人：ENI S.P.A.

  公开号：US20220416169A1

  公开（公告）日：2022-12-29

  There is a polymeric photovoltaic cell (or solar cell) with inverted structure having an anode; an anodic buffer layer; an active layer having at least one photoactive organic polymer as electron-donor and at least one electron-accepting organic compound; a cathodic buffer layer; and a cathode. The at least one photoactive organic polymer is selected from conjugated polymers comprising an anthraditiophenic derivative having a general formula (I): The polymeric photovoltaic cell (or solar cell) with inverted structure shows good values of power conversion efficiency (PCE) (η) and can be advantageously used in the construction of photovoltaic modules (or solar modules), either on a rigid support or on a flexible support.