dysprosium 2,3,9,10,16,17,23,24-tetra(isopropylidenedioxy)phthalocyanine acetate | 672284-67-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并间二氧杂环戊烯类
• 英文名称: dysprosium 2,3,9,10,16,17,23,24-tetra(isopropylidenedioxy)phthalocyanine acetate
• 英文别名: (Me2CO2)4PcDyOAc
• CAS: 672284-67-2
• 化学式: C₄₆H₃₅DyN₈O₁₀
• 分子量: 1022.33
• InChiKey: MUWHNUITEPPAFH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dysprosium(III) acetate 、 5,6-dicyano-2,2-dimethyl-1,3-benzodioxole 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 further solvent(s) 为溶剂， 以48%的产率得到dysprosium 2,3,9,10,16,17,23,24-tetra(isopropylidenedioxy)phthalocyanine acetate
  参考文献：
  名称：

  摘要：

  A series of new metal monophthalocyanine complexes were synthesized from 4,5-iso-propylidenedioxyphthalonitrile and their spectroscopic and electrochemical properties were studied. The removal of the protective isopropylidene groups from these compounds afforded symmetrically substituted octahydroxyphthalocyanines.

  DOI：

  10.1023/a:1025693009575

文献信息

• New diphthalocyanine complexes of rare-earth metals based on 4,5-isopropylidenedioxyphthalonitrile
  作者：A. V. Ivanov、P. A. Svinareva、I. V. Zhukov、L. G. Tomilova、N. S. Zefirov

  DOI：10.1007/s11172-006-0249-4

  日期：2006.2

  A series of the earlier unknown diphthalocyanine complexes of rare-earth metals based on 4,5-isopropylidenedioxyphthalonitrile were prepared. Their compositions and yields depend on the radius of the complexing ion. The synthesized compounds were studied by spectroscopy and electrochemical methods. The redox potentials of the complexes studied change nonlinearly with a decrease in the lanthanide ion radius.

  以 4,5-异亚丙基二氧基邻苯二甲腈为基础，制备了一系列早期未知的稀土金属二酞菁络合物。它们的组成和产量取决于络合离子的半径。通过光谱和电化学方法对合成的化合物进行了研究。所研究的络合物的氧化还原电位随着镧系离子半径的减小而发生非线性变化。