[Mn(p-phthalato)(4,4'-bipyridine)] | 571145-51-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Mn(p-phthalato)(4,4'-bipyridine)]
• CAS: 571145-51-2
• 化学式: C₈H₄O₄*C₁₀H₈N₂*Mn
• 分子量: 375.242
• InChiKey: LQHULMGHNVZJHL-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 manganese(II)carbonate 、 对苯二甲酸 以 乙醇 、 水 为溶剂， 以37%的产率得到[Mn(p-phthalato)(4,4'-bipyridine)]
  参考文献：
  名称：

  Structural transformation mediated by o-, m-, and p-phthalates from two to three dimensions for manganese/phthalate/4,4′-bpy complexes (4,4′-bpy = 4,4′-bipyridine)

  摘要：

  Three isomers of o-, m-, and p-phthalate are used to link together Mn centres, resulting in [Mn(phth)(H2O)x]n moieties (phth = phthalate dianion) with single-chain, double-chain and sheet structures, respectively, which predetermine the extended structures derived from the crosslinkage of 4,4′-bipyridine, and show the influence of isomerism of the phthalate on topological changes of the final polymers from two dimensional (2D) single-layer, double-layer to 3D network architectures. These structural changes in topology are correlated with the differences in the magnetic and optical properties of the polymers.

  DOI：

  10.1039/b301076g