γ-phenylthiopropyl gem-dichlorocyclopropylmethyl ether | 872413-70-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: γ-phenylthiopropyl gem-dichlorocyclopropylmethyl ether
• 英文别名: ({3-[(2,2-Dichlorocyclopropyl)methoxy]propyl}sulfanyl)benzene；3-[(2,2-dichlorocyclopropyl)methoxy]propylsulfanylbenzene
• CAS: 872413-70-2
• 化学式: C₁₃H₁₆Cl₂OS
• 分子量: 291.241
• InChiKey: MLFFQYOUJQUYBD-UHFFFAOYSA-N

物化性质

• 沸点：
  144 °C(Press: 3 Torr)
• 密度：
  1.1930 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  34.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯硫酚 、 2-(allyloxymethyl)-1,1-dichlorocyclopropane 在 偶氮二异丁腈 作用下， 反应 2.0h， 以85%的产率得到γ-phenylthiopropyl gem-dichlorocyclopropylmethyl ether
  参考文献：
  名称：

  Chlorocyclopropane-containing sulfides as additives for lubricating oils

  摘要：

  Chlorocyclopropane-containing sulfides were synthesized via the radical-initiated reaction of thiophenol and ethanedithiol with vinyl(allyl)-gem-dichlorocyclopropyl ethers and characterized. The antiwear and extreme-pressure properties of the synthesized adducts were studied, and these compounds were shown to be effective additives for lubricating oils.

  DOI：

  10.1134/s0965544106030121

文献信息

• Chlorocyclopropane-containing sulfides as additives for lubricating oils
  作者：R. Z. Shakhnazarli、S. S. Gasanova、A. M. Guliev

  DOI：10.1134/s0965544106030121

  日期：2006.5

  Chlorocyclopropane-containing sulfides were synthesized via the radical-initiated reaction of thiophenol and ethanedithiol with vinyl(allyl)-gem-dichlorocyclopropyl ethers and characterized. The antiwear and extreme-pressure properties of the synthesized adducts were studied, and these compounds were shown to be effective additives for lubricating oils.