[(GaCl₃)*pyrazine]n | 882552-59-2

• 分子结构分类: 有机化合物
• 英文名称: [(GaCl₃)*pyrazine]n
• 英文别名: [GaCl3(pyrazine)]n；GaCl3(pyrazine)；[GaCl3(pyz)]n；pyrazine;trichlorogallane
• CAS: 882552-59-2
• 化学式: C₄H₄Cl₃GaN₂
• 分子量: 256.171
• InChiKey: BVKKSZZNPSEJNT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡嗪 、 氯化镓 生成 [(GaCl₃)*pyrazine]n
  参考文献：
  名称：

  Thermodynamic Characteristics of Gaseous GaCl3pyz and GaCl3pyzGaCl3 Complexes

  摘要：

  利用带有膜片零压计的静态张力法测定了配合物GaCl3pyz和GaCl3pyzGaCl3（pyz是吡嗪）的汽化及气相解离的热力学特性。通过B3LYP/pVDZ量子化学方法计算了配合物的结构和热力学特性。

  DOI：

  10.1007/s11176-005-0391-y

文献信息

• From gallium to thallium: Group 13 one-dimensional polymers
  作者：Christian R. Samanamú、Peter M. Lococo、Anne F. Richards

  DOI：10.1016/j.ica.2007.03.048

  日期：2007.11

  The reactions of EX3 (E = Ga, In, Tl, X = Br or Cl) with pyrazine and pyrazine, 2-carboxylic acid (pyzea-H) affords a series of one-dimensional ladder polymers, [EX3(PYZ)](infinity) (E = Ga, In, Tl, X = Cl, Br) and the zigzag polymer [InBr2(OH2)(2)(pyzca)](infinity). These polymers are prepared in high yield through a facile synthesis. The structures of each were characterized in the solid state by single crystal X-ray analysis, infrared spectroscopy and where possible NMR. Experimental results reveal how stability of the one-dimensional polymer increases from gallium to thallium, from the air-sensitive gallium polymer to the aqueous preparation and air-stable products of indium and thallium. (c) 2007 Elsevier B.V. All rights reserved.