[(Pd(N,N-dimethylbenzylamine)(NO3))2(μ-pirazine)] | 1132786-84-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [(Pd(N,N-dimethylbenzylamine)(NO3))2(μ-pirazine)]
• CAS: 1132786-84-5
• 化学式: C₂₂H₂₈N₆O₆Pd₂
• 分子量: 685.341
• InChiKey: UBMWRECMUFQZCD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡嗪 、 [Pd(N,N-dimethylbenzylamine)(acetonitrile)2](NO3) 以 二氯甲烷 为溶剂， 以80%的产率得到[(Pd(N,N-dimethylbenzylamine)(NO3))2(μ-pirazine)]
  参考文献：
  名称：

  Synthesis and characterization of mono and polymeric cyclopalladated compounds: Crystal and molecular structure of [{Pd(dmba)(ONO2)}2(μ-pz)]·H2O (pz=pyrazine)

  摘要：

  In the treatment of cyclometallated dimer [Pd(dmba)(mu-Cl)](2) (dmba = N,N-dimethylbenzylamine) with AgNO3 and acetonitrile the result was the monomeric cationic precursor [Pd(dmba)(NCMe)(2)](NO3) (NCMe=acetonitrile) (1). Compound 1 reacted with m-nitroaniline (m-NAN) and pirazine (pz), originating [Pd(dmba)(ONO2)(m-NAN)] (2) and [{Pd(dmba)(ONO2)}(2)(mu-pz)] center dot H2O (3), respectively. These compounds were characterized by elemental analysis, IR and NMR spectroscopy. The IR spectra of (2-3) display typical bands of monodentade O-bonded nitrate groups, whereas the NMR data of 3 are consistent with the presence of bridging pyrazine ligands. The structure of compound 3 was determined by Xray diffraction analysis. This packing consists of a supramolecular chain formed by hydrogen bonding between the water molecule and nitrato ligands of two consecutive [Pd-2(dmba)(2)(ONO2)2(mu-pz)] units. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.048