[Au(C2CMe(Et)OH)(1,3,5-triaza-7-phosphaadamantane)] | 876069-42-0

• 分子结构分类: 有机化合物
• 英文名称: [Au(C2CMe(Et)OH)(1,3,5-triaza-7-phosphaadamantane)]
• 英文别名: Au(CC(Me)(Et)OH)(1,3,5-triaza-7-phosphaadamantane)；Au(CCC(Me)(Et)OH)(PTA)
• CAS: 876069-42-0
• 化学式: C₁₂H₂₁AuN₃OP
• 分子量: 451.259
• InChiKey: VFKKYAYNZXSGNN-MPDITTGVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [AuCl(PTA)] 、 3-甲基-1-戊炔-3-醇 在 NaOC₂H₅ 作用下， 以 乙醇 为溶剂， 以86%的产率得到[Au(C2CMe(Et)OH)(1,3,5-triaza-7-phosphaadamantane)]
  参考文献：
  名称：

  Organometallic Gold(I) and Gold(III) Complexes Containing 1,3,5-Triaza-7-phosphaadamantane (TPA):  Examples of Water-Soluble Organometallic Gold Compounds

  摘要：

  The organometallic gold(l) complexes [Au(C equivalent to CCRR'OH)(TPA)] (R = R, = H, Me, Ph and R = Me, R' = Et) and [Au(C6F5)(TPA)] as well as the gold(Ill) complexes trans-[Au(C6F5)(2)(TPA)(2)]OTf and [Au(C6F5)(3)(TPA)] (TPA = 1,3,5-triaza-7-phosphaadamantane) were prepared and fully characterized by spectroscopic methods and, in the case of rac- [Au{C equivalent to C(Et)(Me)OH} (TPA)] and [Au(C6F5)(3)(TPA)], by X-ray crystallography. The alkynyl complexes [Au(C equivalent to CCRR'OH)(TPA)] (R = R, = H, Me and R = Me, R' = Et) represent rare examples of organometallic gold(l) complexes that are soluble and stable in water.

  DOI：

  10.1021/om050852d