| 192865-78-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 192865-78-4
• 化学式: C₇H₁₀N*C₁₈H₁₀S₁₀Sb
• 分子量: 776.851
• InChiKey: HMACURFOQMQULP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diphenylstibine trichloride hydrate 、 bis(1,4-dimethyl-pyridinium) bis(1,3-dithiole-2-thione-4,5-dithiolato)zincate 、 potassium thioacyanate 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  [Bis(1,3-dithiole-2-thione-4,5- dithiolato)diarylantimonate(1-)], [Ar2Sb(dmit)2]−, complexes. Crystal structures of [NEt4][Ar2Sb(dmit)2] (Ar = Ph or p-tolyl)

  摘要：

  The ionic complexes [Q][Ph2Sb(dmit)(2)] (4; Q = NEt4 or 1,4-Me-2-pyridinium) and [Net(4)][(p-tolyl)(2)Sb(dmit)(2)] (5) have been prepared from [Q](2)[Zn(dmit)(2)] and Ar2SbCl3 in the presence of KSCN (H-2-dmit = 4,5-dimercapto-1,3-dithiole-2-thione). As shown by X-ray crystallography for 4 (Q = NEt4) and 5, these complexes contain distorted octahedral anions with cis-aryl groups : the C-Sb-C angles in 4 (Q = NEt4) and 5 are 93.1(2) and 95.3(5)degrees, respectively. The dmit chelates are unsymmetrically bonded to antimony in both 4 (Q = NEt4) and 5 with the longer bonds trans to the aryl groups (for both compounds, the Sb-S bond lengths are in the ranges, 2.614 to 2.636 and 2.530-2.550 Angstrom). (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00004-1