| 1227358-21-5

• 分子结构分类: 有机化合物
• CAS: 1227358-21-5；1227358-22-6；1227358-23-7；166542-40-1
• 化学式: C₆₀*Pd
• 分子量: 827.08
• InChiKey: RBWSUYQAKYSXAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.87
• 重原子数：
  61.0
• 可旋转键数：
  0.0
• 环数：
  32.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  、 反应 2.0h， 以0.051 g的产率得到
  参考文献：
  名称：

  Catalytic comparison of Pd-C60 complex and its non-fullerene form bearing phosphorus ylide in C C coupling reactions

  摘要：

  DOI：

  10.1016/j.poly.2021.115637
• 作为产物：
  描述：

  足球烯 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 以 甲苯 为溶剂， 反应 0.5h， 生成
  参考文献：
  名称：

  Catalytic comparison of Pd-C60 complex and its non-fullerene form bearing phosphorus ylide in C C coupling reactions

  摘要：

  DOI：

  10.1016/j.poly.2021.115637

文献信息

• C60Pd n : the first organometallic polymer of buckminsterfullerene
  作者：Hideo Nagashima、Akihito Nakaoka、Yahachi Saito、Masanao Kato、Teruhiko Kawanishi、Kenji Itoh

  DOI：10.1039/c39920000377

  日期：——

  The organometallic polymer, C60Pdn, is prepared from C60 and a Pd0 precursor, and the palladium to C60 ratio (n) can be varied by thermal disproportionation.

  有机金属聚合物 C60Pdn 由 C60 和 Pd0 前体制备而成，钯与 C60 的比例（n）可通过热歧化来改变。
• Study of Redox Active C[sub 60]/Pd Films by Simultaneous Cyclic Voltammetry and Piezoelectric Microgravimetry at an Electrochemical Quartz Crystal Microbalance
  作者：Krzysztof Winkler、Krzysztof Noworyta、Wlodzimierz Kutner、Alan L. Balch

  DOI：10.1149/1.1393574

  日期：——

  The formation and properties of redox active C 60 /Pd films on gold electrodes of quartz oscillators were investigated by simultaneous cyclic voltammetry and piezoelectric microgravimetry at a quartz crystal microbalance. The films were prepared by electroreduction of solutions of C 60 and [Pd II (CH 3 COO) 2 ] 3 in 0.1 mol dm -3 tetra(n-butyl)ammonium perchlorate in acetonitrile-toluene (1:4, v:v)

  通过同时循环伏安法和压电微重力法在石英晶体微天平上研究了氧化还原活性 C 60 /Pd 薄膜在石英振荡器金电极上的形成和性质。通过电还原 C 60 和 [Pd II (CH 3 COO) 2 ] 3 在 0.1 mol dm -3 四（正丁基）高氯酸铵的乙腈-甲苯 (1:4, v:v) 中的溶液制备薄膜. 制备薄膜的溶液的组成显着影响薄膜生长的模式。目前的结果证实，如果钯络合物与C 60 的比率高，则钯簇与C 60 /Pd 膜共沉积。还原的聚合物膜在足够负的电位范围内变得部分电化学失活。然而，这种电惰性薄膜可以在非常正的电位下被氧化。对于电荷补偿，四（正丁基）铵抗衡阳离子在其电还原过程中进入薄膜，并在电氧化过程中从薄膜中排出。在相对较高的潜在扫描速率下，只有与沐浴液直接接触的薄膜最外层才具有电化学活性。然而，在低扫描速率下，体膜材料也是活性的。在非常负的电位下，薄膜会从电极上移除。四(n-烷基)铵抗衡阳离子的大小是决定C
• Dehydrogenation of compounds with weakened C-H bonds in the presence of platinum and palladium fullerides
  作者：G. N. Boiko、Yu. M. Shul’ga、O. S. Roshchupkina、A. S. Lobach、N. F. Gol’dshleger

  DOI：10.1134/s1070363207040214

  日期：2007.4

  Coordinated fullerene acts as a hydrogen acceptor in reactions with compounds having weakened C-H bonds (1,4-dihydropyridine and 9,10-dihydroanthracene). Metal fullerides are the dehydrogenation catalysts. They activate the C-H bonds of dihydroanthracene and diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate in positions 9,10 and 1,4, respectively. No activation of norbornane carbon-hydrogen bonds with metal fullerides was observed under mild conditions.
• Single-stage plasma-arc synthesis of metallo-endofullerences
  作者：V. I. Gerasimov、G. V. Kalinin、Yu. A. Nikonov、Yu. F. Titovets、A. E. Kalabushkin、O. S. Alekhin、K. V. Nekrasov、S. N. Rusetskaya、O. V. Arapov、N. I. Alekseev、E. V. Kustova、V. V. Lishchuk、M. A. Pleshkov、K. N. Semenov、V. A. Keskinov、N. A. Charykov

  DOI：10.1134/s1070427207110213

  日期：2007.11

  Single-stage plasma-arc synthesis of metallo-endofullerenes of the types C60Pd, C60Ni, and C60Cr, whose content in a mixture of extracted fullerenes was 0.05 to 0.15 wt %, was performed. The effect of introduction of these metals into the reaction plasma on the total yield of fullerenes and on the fraction composition of the fullerene mixture was studied. The fullerene mixtures were analyzed by mass spectrometry and liquid chromatography.
• Measurement of third-order optical nonlinearity of C60M2 (M=Pd, Pt, and Sm) organometallic compounds by the femtosecond optically heterodyned optical Kerr effect
  作者：Wei Qian、Li Lin、Zongju Xia、Yinghua Zou、Shixiong Qian、Guohong Ma、Yanghui Lin、Ruifang Cai、Yu Chen、Zu-En Huang

  DOI：10.1016/s0009-2614(00)00074-9

  日期：2000.3

  We have measured the real components of the third-order optical nonlinearity of organometallic compound films of C60M2 (M = Pd, Pt, and Sm) by using the femtosecond optically heterodyned optical Kerr effect at 647.0 nm. The results show that there is an enhancement of the real components of the third-order optical nonlinearity of C60M2 films compared to that of pristine C-60 film. We attribute the origin of this enhancement to the charge transfer from the metal atoms to the C-60 molecules. (C) 2000 Elsevier Science B.V. All rights reserved.