2,2'-divinyl-4,4'-biphenol | 784208-80-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2'-divinyl-4,4'-biphenol
• 英文别名: 3-Ethenyl-4-(2-ethenyl-4-hydroxyphenyl)phenol；3-ethenyl-4-(2-ethenyl-4-hydroxyphenyl)phenol
• CAS: 784208-80-6
• 化学式: C₁₆H₁₄O₂
• 分子量: 238.286
• InChiKey: YSRPFWBWSLJQPV-UHFFFAOYSA-N

物化性质

• 沸点：
  452.3±45.0 °C(Predicted)
• 密度：
  1.171±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2'-divinyl-4,4'-biphenol 、 1-(Bromomethyl)-4-[4-[[4-[4-[1-[1-[1-[1-[1-[1-[1-[1-[1-[1-[1-[1-[1-[1-[1-[1-(1-methoxypropan-2-yloxy)propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]propan-2-yloxy]phenyl]phenoxy]methyl]phenyl]benzene 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 12.0h， 以55%的产率得到
  参考文献：
  名称：

  Shape-Persistent Macromolecular Disks from Reactive Supramolecular Rod Bundles

  摘要：

  We have synthesized a coil-rod-coil molecule based on a reactive rod block that self-organizes into a 3-D hexagonal close-packed (hcp) bundle structure in the melt state. Photo-cross-linking within an aromatic bundle yielded macromolecular disklike objects (molecular weight of 330 kDa) with a narrow size distribution that was essentially the same as that of the supramolecular bundles. In addition, cross-linking proceeded with the retention of the 3-D hcp symmetry of the supramolecular bundles. The 3-D symmetry of the macromolecular objects was observed to recover after their isolation from the solutions and transform into an isotropic liquid in the bulk state in a reversible way, suggesting that the macromolecular objects are shape-persistent in solutions as well as an isotropic liquid phase of the bulk.

  DOI：

  10.1021/ja0465552
• 作为产物：
  描述：

  2,2'-dimethyl-4,4'-diacetoxybiphenyl 在 sodium hydroxide 、 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 甲醇 、 四氯化碳 、 丙酮 为溶剂， 反应 21.0h， 生成 2,2'-divinyl-4,4'-biphenol
  参考文献：
  名称：

  Shape-Persistent Macromolecular Disks from Reactive Supramolecular Rod Bundles

  摘要：

  We have synthesized a coil-rod-coil molecule based on a reactive rod block that self-organizes into a 3-D hexagonal close-packed (hcp) bundle structure in the melt state. Photo-cross-linking within an aromatic bundle yielded macromolecular disklike objects (molecular weight of 330 kDa) with a narrow size distribution that was essentially the same as that of the supramolecular bundles. In addition, cross-linking proceeded with the retention of the 3-D hcp symmetry of the supramolecular bundles. The 3-D symmetry of the macromolecular objects was observed to recover after their isolation from the solutions and transform into an isotropic liquid in the bulk state in a reversible way, suggesting that the macromolecular objects are shape-persistent in solutions as well as an isotropic liquid phase of the bulk.

  DOI：

  10.1021/ja0465552

文献信息

• Ordered Nanostructures from the Self-Assembly of Reactive Coil-Rod-Coil Molecules
  作者：Long Yi Jin、Jinyoung Bae、Ja-Hyoung Ryu、Myongsoo Lee

  DOI：10.1002/anie.200502911

  日期：2006.1.16
• Shape-Persistent Macromolecular Disks from Reactive Supramolecular Rod Bundles
  作者：Long Yi Jin、Jong-Hyun Ahn、Myongsoo Lee

  DOI：10.1021/ja0465552

  日期：2004.10.1

  We have synthesized a coil-rod-coil molecule based on a reactive rod block that self-organizes into a 3-D hexagonal close-packed (hcp) bundle structure in the melt state. Photo-cross-linking within an aromatic bundle yielded macromolecular disklike objects (molecular weight of 330 kDa) with a narrow size distribution that was essentially the same as that of the supramolecular bundles. In addition, cross-linking proceeded with the retention of the 3-D hcp symmetry of the supramolecular bundles. The 3-D symmetry of the macromolecular objects was observed to recover after their isolation from the solutions and transform into an isotropic liquid in the bulk state in a reversible way, suggesting that the macromolecular objects are shape-persistent in solutions as well as an isotropic liquid phase of the bulk.