2-(4'-methylphenyliminomethinyl)phenyltellurenyl bromide | 130191-28-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4'-methylphenyliminomethinyl)phenyltellurenyl bromide
• 英文别名: 2-bromotelurenylbenzal-4'-methylaniline；2-{[(4-Methylphenyl)imino]methyl}benzenetellurenyl bromide；[2-[(4-methylphenyl)iminomethyl]phenyl] tellurohypobromite
• CAS: 130191-28-5
• 化学式: C₁₄H₁₂BrNTe
• 分子量: 401.76
• InChiKey: QPXBEYFUTBHMIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.39
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(4'-methylphenyliminomethinyl)phenyltellurenyl bromide 在 sodium azide 作用下， 以 氯仿 、 水 为溶剂， 以82%的产率得到2-azidotellurenylbenzal-4'-methylaniline
  参考文献：
  名称：

  Chemical consequences of intramolecular Te ← N coordination in tellurium-containing aromatic azomethine derivatives

  摘要：

  DOI：

  10.1016/0022-328x(90)80172-v
• 作为产物：
  描述：

  (2-formylphenyl)butyl tellurium dibromide 、 乙烷,三氯氟- 在 三氟乙酸 作用下， 以 苯 为溶剂， 以100%的产率得到2-(4'-methylphenyliminomethinyl)phenyltellurenyl bromide
  参考文献：
  名称：

  Chemical consequences of intramolecular Te ← N coordination in tellurium-containing aromatic azomethine derivatives

  摘要：

  DOI：

  10.1016/0022-328x(90)80172-v

文献信息

• Aspects of the chemistry of diorgano tritellurides
  作者：Anatoly G. Maslakov、Martin R. Greaves、William R. McWhinnie、Sean L.W. McWhinnie

  DOI：10.1016/0022-328x(94)80040-5

  日期：1994.4

  The synthetic methods available for diorgano tritellurides, which normally give only poor to moderate yields of product, are evaluated. Most reliable when organic groups such as 2-(2'-pyridyl)phenyl- are involved is the reaction of Te2- with the organotellurenyl halide in DMF. Other methods require a final oxidative step. Reactions of Te-2(2-) with organotellurenyl halides in DMF give deep red solutions which quantitatively deposit tellurium on exposure to air; successful syntheses of (RTe)2Se2 (R = 2-(2'-pyridyl or 2'-quinolinyl)phenyl-) were carried out by use of Se-2(2-) in DMF solution. The air stable bis-[2-(p-tolyliminomethyl)phenyl] tritelluride is reported, and its Te-125 and Raman spectral data presented. The role of intra-molecular coordination in stabilising these molecules may be a secondary one; the steric effect of a bulky 2-substituent on the tellurated phenyl-ring may be more significant.
• Chemical consequences of intramolecular Te ← N coordination in tellurium-containing aromatic azomethine derivatives
  作者：I.D. Sadekov、A.A. Maksimenko、A.G. Maslakov、V.I. Minkin

  DOI：10.1016/0022-328x(90)80172-v

  日期：1990.7