2,2'-[2,2'-methylenebis(4-methyl-1-phenoxy)]bis-[2,10-dimethyl-12H-dibenzo[d,g]-1,3,2-dioxaphosphocine] | 501424-73-3

• 分子结构分类: 有机化合物
• 英文名称: 2,2'-[2,2'-methylenebis(4-methyl-1-phenoxy)]bis-[2,10-dimethyl-12H-dibenzo[d,g]-1,3,2-dioxaphosphocine]
• CAS: 501424-73-3
• 化学式: C₄₅H₄₂O₆P₂
• 分子量: 740.772
• InChiKey: NXPPRUKBSHEWPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.46
• 重原子数：
  53.0
• 可旋转键数：
  6.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  55.38
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  acetylacetonatodicarbonylrhodium(l) 、 2,2'-[2,2'-methylenebis(4-methyl-1-phenoxy)]bis-[2,10-dimethyl-12H-dibenzo[d,g]-1,3,2-dioxaphosphocine] 以 苯 为溶剂， 以84%的产率得到[2,2'-[2,2'-methylenebis(4-methyl-1-phenoxy)]bis-[2,10-dimethyl-12H-dibenzo[d,g]-1,3,2-dioxaphosphocin-2-yl]]rhodium acetylacetonate
  参考文献：
  名称：

  摘要：

  New types of oligomethylenephenol cyclophosphites containing 1-3 phosphorus atoms are synthesized by reactions of available oligomethylenephenols with phosphorous acid amides. Contrary to their simple analogs, the resulting phosphites are stable on handling, which allowed design on their basis of complex coordination systems holding promise for metal complex catalysis.

  DOI：

  10.1023/a:1020430206758
• 作为产物：
  描述：

  对甲酚 、 alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 作用下， 以 水 、 苯 为溶剂， 反应 10.0h， 生成 2,2'-[2,2'-methylenebis(4-methyl-1-phenoxy)]bis-[2,10-dimethyl-12H-dibenzo[d,g]-1,3,2-dioxaphosphocine]
  参考文献：
  名称：

  摘要：

  New types of oligomethylenephenol cyclophosphites containing 1-3 phosphorus atoms are synthesized by reactions of available oligomethylenephenols with phosphorous acid amides. Contrary to their simple analogs, the resulting phosphites are stable on handling, which allowed design on their basis of complex coordination systems holding promise for metal complex catalysis.

  DOI：

  10.1023/a:1020430206758