dicamba N,N-bis(3-aminopropyl)methylamine salt | 2140854-81-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dicamba N,N-bis(3-aminopropyl)methylamine salt
• 英文别名: Engenia；dicamba BAPMA salt；Dicamba biproamine；N'-(3-aminopropyl)-N'-methylpropane-1,3-diamine;3,6-dichloro-2-methoxybenzoic acid
• CAS: 2140854-81-3
• 化学式: C₇H₁₉N₃*C₈H₆Cl₂O₃
• 分子量: 366.288
• InChiKey: XNYCXKRWVHWIBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.32
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  102
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  N,N-双(3-氨丙基)甲胺 、 麦草畏 以 甲醇 为溶剂， 25.0 ℃ 、101.3 kPa 条件下， 以92%的产率得到dicamba N,N-bis(3-aminopropyl)methylamine salt
  参考文献：
  名称：

  基于Dicamba的除草剂：除草离子液体与商业形式。

  摘要：

  麦草畏是广泛用于农作物保护的除草剂，具有潜在的挥发性。2017年投放市场的含有麦草畏的大幅降低了挥发性的新制剂，仍然对美国阿肯色州和邻国的农作物和其他植物造成叶面伤害。作为回应，我们提出了将麦草畏转变为质子以及基于麦草畏的基于麦草畏的有机盐的除草离子液体（HILs）。所有HIL均具有高稳定性，而在温室研究过程中评估的最有效产品的生物活性却高于目前使用的商业类似物。此外，引入特定长度的烷基链的可能性允许人们获得具有所需理化性质同时保持除草效果的植物保护产物。预期这些研究将有助于新除草剂配方的设计和开发，这取决于杂草种类，可提高所用活性成分的功效。同时，合成化合物的挥发性，特别是那些含有季铵阳离子的化合物的挥发性，比麦草畏的游离酸低很多倍。该策略最大程度地减少了因挥发而异地移动的风险，该风险可能会对邻近的阔叶作物造成重大破坏，并对现有生态系统构成威胁。预期这些研究将有助于新除草剂配方的设计和开

  DOI：

  10.1021/acs.jafc.0c00632

文献信息

• METHOD FOR CONTROLLING HERBICIDE-RESISTANT WEED
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20220322665A1

  公开（公告）日：2022-10-13

  Provided is a method for effectively controlling specific weeds having resistance to herbicides. The method comprises applying one or more uracil compounds selected from a group consisting of a compound represented by formula (I): and a compound represented by formula (II): to a PPO inhibitor-resistant weed which has one or more mutations selected from a group consisting of Arg128Met mutation, Arg128Gly mutation, Arg128His mutation, Arg128Ile mutation, Arg128Lys mutation, and Gly399Ala mutation in PPO.

  提供了一种有效控制对除草剂具有抗性的特定杂草的方法。该方法包括将选择自公式（I）所表示的化合物和自公式（II）所表示的化合物之一的一种或多种尿嘧啶化合物应用于具有PPO抑制剂抗性杂草上，该杂草在PPO中具有从Arg128Met突变、Arg128Gly突变、Arg128His突变、Arg128Ile突变、Arg128Lys突变和Gly399Ala突变中选择的一种或多种突变。
• HERBICIDAL MIXTURES COMPRISING ISOXAFLUTOLE, PYROXASULFONE AND AN IMIDAZOLINONE HERBICIDE; AND THEIR USE IN SOYBEAN AND COTTON CULTURES
  申请人：BASF SE

  公开号：EP3603399A1

  公开（公告）日：2020-02-05

  The present invention relates to herbicidal mixtures comprising isoxaflutole, pyroxasulfone and an imidazolinone herbicide. The herbicidal mixtures may comprise at least one further herbicide selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinate-P) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, bicyclopyrone, fenquinotrione, mesotrione, tembotrione, tolpyralate and toprame-zone. Furthermore, the invention relates to methods and uses applying the herbicidal mixtures, especially for controlling undesirable vegetation in in soybean and cotton cultures.

  本发明涉及由异噁唑草酮、吡唑醚菌酯和咪唑啉酮类除草剂组成的除草混合物。除草混合物还可包含至少一种除草剂，该除草剂选自草甘膦及其盐类、草胺膦及其盐类、L-草胺膦（草胺膦-P）及其盐类、麦草畏及其盐类和酯类、2,4-D 及其盐类和酯类、双环草醚、喹啉草酮、间苯三酚、丁草胺、甲基吡啶甲酸盐和toprame-zone。此外，本发明还涉及应用除草混合物的方法和用途，特别是用于控制大豆和棉花栽培中的不良植被。
• HERBICIDAL MIXTURES COMPRISING ISOXAFLUTOLE, DIMETHENAMID OR DIMETHENAMID-P AND AN IMIDAZOLI-NONE HERBICIDE; AND THEIR USE IN SOYBEAN AND COTTON CULTURES
  申请人：BASF SE

  公开号：EP3603395A1

  公开（公告）日：2020-02-05

  The present invention relates to herbicidal mixtures comprising isoxaflutole, dimethenamid or dimethenamid-P and an imidazolinone herbicide. The herbicidal mixtures may comprise at least one further herbicide selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinate-P) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, bicyclopyrone, fenquinotrione, mesotrione, tembotrione, tolpyralate and topramezone. Furthermore, the invention relates to methods and uses applying the herbicidal mixtures, especially for controlling undesirable vegetation in in soybean and cotton cultures.

  本发明涉及由异噁唑草酮、二甲戊灵或二甲戊灵-P 和一种咪唑啉酮类除草剂组成的除草混合物。除草混合物还可包括至少一种除草剂，该除草剂选自草甘膦及其盐类、草胺膦及其盐类、L-草胺膦（草胺膦-P）及其盐类、麦草畏及其盐类和酯类、2,4-D 及其盐类和酯类、双环草醚、喹草酮、间喹草酮、丁草胺、托吡酯和托吡酮。此外，本发明还涉及应用除草混合物的方法和用途，特别是用于控制大豆和棉花栽培中的不良植被。
• HERBICIDAL MIXTURES COMPRISING ISOXAFLUTOLE, SAFLUFENACIL AND AN IMIDAZOLINONE HERBICIDE; AND THEIR USE IN SOYBEAN AND COTTON CULTURES
  申请人：BASF SE

  公开号：EP3603396A1

  公开（公告）日：2020-02-05

  The present invention relates to herbicidal mixtures comprising isoxaflutole, saflufenacil and an imidazolinone herbicide. The herbicidal mixtures may comprise at least one further herbicide selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinate-P) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, bicyclopyrone, fenquinotrione, mesotrione, tembotrione, tolpyralate and topramezone. Furthermore, the invention relates to methods and uses applying the herbicidal mixtures, especially for controlling undesirable vegetation in in soybean and cotton cultures.

  本发明涉及由异噁唑草酮、氟虫腈和咪唑啉酮类除草剂组成的除草混合物。除草混合物还可包含至少一种除草剂，该除草剂选自草甘膦及其盐类、草胺膦及其盐类、L-草胺膦（草胺膦-P）及其盐类、麦草畏及其盐类和酯类、2,4-D 及其盐类和酯类、双环草醚、喹禾灵、间喹禾灵、丁草胺、托吡酯和托吡酮。此外，本发明还涉及应用除草混合物的方法和用途，特别是用于控制大豆和棉花栽培中的不良植被。
• HERBICIDAL MIXTURES COMPRISING ISOXAFLUTOLE, TRIFLUDIMOXAZIN AND AN IMIDAZOLINONE HERBICIDE; AND THEIR USE IN SOYBEAN AND COTTON CULTURES
  申请人：BASF SE

  公开号：EP3603397A1

  公开（公告）日：2020-02-05

  The present invention relates to herbicidal mixtures comprising isoxaflutole, trifludimoxazin and an imidazolinone herbicide. The herbicidal mixtures may comprise at least one further herbicide selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinate-P) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, bicyclopyrone, fenquinotrione, mesotrione, tembotrione, tolpyralate and topramezone. Furthermore, the invention relates to methods and uses applying the herbicidal mixtures, especially for controlling undesirable vegetation in in soybean and cotton cultures.

  本发明涉及由异噁唑草酮、三氟草胺和咪唑啉酮除草剂组成的除草混合物。除草混合物还可包含至少一种除草剂，该除草剂选自草甘膦及其盐类、草胺膦及其盐类、L-草胺膦（草胺膦-P）及其盐类、麦草畏及其盐类和酯类、2,4-D 及其盐类和酯类、双环草醚、喹禾灵、间喹禾灵、丁草胺、托吡酯和托吡酮。此外，本发明还涉及应用除草混合物的方法和用途，特别是用于控制大豆和棉花栽培中的不良植被。