tert-butyl 4-aminobenzyl ether | 1039311-45-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tert-butyl 4-aminobenzyl ether
• 英文别名: 4-[(Tert-butoxy)methyl]aniline；4-[(2-methylpropan-2-yl)oxymethyl]aniline
• CAS: 1039311-45-9
• 化学式: C₁₁H₁₇NO
• mdl: MFCD11196358
• 分子量: 179.262
• InChiKey: CCZARLXYZZERPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.454
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-(tert-butoxymethyl)-4-nitrobenzene 在 氢气 作用下， 以 甲醇 为溶剂， 20.0 ℃ 、101.33 kPa 条件下， 反应 2.0h， 以98%的产率得到tert-butyl 4-aminobenzyl ether
  参考文献：
  名称：

  Chemoselective hydrogenation of nitrobenzyl ethers to aminobenzyl ethers catalyzed by palladium–nickel bimetallic nanoparticles

  摘要：

  A highly efficient and chemoselective hydrogenation of nitrobenzyl ethers to aminobenzyl ethers was developed by using a novel palladium nickel bimetallic nanocatalyst. Since the catalytic selectivity was resulted from the synergistic effects between two metals rather than the traditional catalyst poisons, the hydrogenation proceeded smoothly under additive-free conditions. Thus, the work-up procedure was as simple as to recover the catalyst by a magnetic separation and then to evaporate the solvent. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.10.037

文献信息

• Synthesis of Homopolymers and Block Copolymers
  申请人：Breitenkamp Kurt

  公开号：US20110124840A1

  公开（公告）日：2011-05-26

  The present invention relates to the field of polymer chemistry and more particularly to homopolymers and block copolymers and methods of preparing the same.
• SYNTHESIS OF HOMOPOLYMERS AND BLOCK COPOLYMERS
  申请人：Breitenkamp Kurt

  公开号：US20120196989A1

  公开（公告）日：2012-08-02

  The present invention relates to the field of polymer chemistry and more particularly to homopolymers and block copolymers and methods of preparing the same.