1,4-Bis-(2-chloro-propyl)-benzene | 92167-85-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-Bis-(2-chloro-propyl)-benzene
• 英文别名: 1,4-Bis(2-chloropropyl)benzene
• CAS: 92167-85-6
• 化学式: C₁₂H₁₆Cl₂
• 分子量: 231.165
• InChiKey: VTPZYPSGKCZDJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Process for the preparation of dimethylketene and then of polydimethylketene fro isobutyric anhydride
  申请人：Hub Serge

  公开号：US20060270878A1

  公开（公告）日：2006-11-30

  The present invention relates to a process for the preparation of dimethylketene (DMK) and then of polydimethylketene (PDMK) by polymerization of DMK. More specifically, the DMK is obtained by pyrolysis by isobutyric anhydride (IBAN), the latter decomposing under the effect of heat (pyrolysis) to give isobutyric acid (IBA) and DMK. One mole of pyrolyzed IBAN gives one mole of IBA and one mole of DMK.

  本发明涉及一种通过二甲基酮（DMK）的聚合制备二甲基酮（DMK）然后聚二甲基酮（PDMK）的过程。更具体地说，DMK是通过异丁酸酐（IBAN）的热解得到的，后者在热量作用下（热解）分解为异丁酸（IBA）和DMK。热解的IBAN生成一摩尔的IBA和一摩尔的DMK。
• Process for the preparation of polymeric tertiary aralkyl isocyanates from 1,3- or 1,4-bis(1-chloro-1-methylethyl)benzene
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0164521A1

  公开（公告）日：1985-12-18

  A process for forming useful oligomers and higher homopolymers of 1,3- or 1,4- bis(1-chloro-1-methylethyl)benzene is disclosed which comprises polymerizing a 1,3- or 1,4-bis(1-chloro-1-methylethyl) benzene and an alkali metal or an alkaline earth metal cyanate in a solvent for the organic reactant and the substantial absence of a catalyst at temperatures of between about 15°C. and about 60°C. until formation of the oligomers and homopolymers is substantially complete. The oligomers and homopolymers produced are related to poly-TMI type polymers and are useful together with active polyurethane coating and or injection moldable compositions.

  本发明公开了一种形成有用的 1，3-或 1，4-双(1-氯-1-甲基乙基)苯的低聚物和高级均聚物的工艺，该工艺包括在有机反应物的溶剂中，在基本不使用催化剂的情况下，在约 15°C 至约 60°C 的温度下，使 1，3-或 1，4-双(1-氯-1-甲基乙基)苯和碱金属或碱土金属氰酸酯聚合，直至低聚物和均聚物的形成基本完成。生成的低聚物和均聚物与聚 TMI 型聚合物有关，可与活性聚氨酯涂层和或注塑组合物一起使用。
• Moisture curable polyisobutylenes
  申请人：DOW CORNING CORPORATION

  公开号：EP0320259A2

  公开（公告）日：1989-06-14

  This invention provides novel moisture curable liquid isobutylene oligomers containing terminal groups of the formula where R represents a monovalent hydrocarbon or halogenated hydrocarbon radical, R′ represents an alkylene radical, X is a hydrolyzable group bonded to silicon through oxygen or nitrogen, and n represents an integer from 1 to 5, inclusive. The invention also provides a method for preparing these oligomers by the hydrosilation of terminally unsaturated isobutylene oligomers with a siloxane of the general formula in the presence of a platinum-containing hydrosilation catalyst.

  本发明提供了新型湿气固化液态异丁烯低聚物，其含有式中的末端基团 其中 R 代表单价烃基或卤代烃基，R′代表亚烷基，X 是通过氧或氮与硅键合的可水解基团，n 代表 1 至 5（包括 5）的整数。本发明还提供了一种制备这些低聚物的方法，即在通式为 在含铂氢化催化剂存在下进行氢化。
• Tackifier composition
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0479311A2

  公开（公告）日：1992-04-08

  A tackifier composition comprising (a) 100 parts by weight of a block copolymer composed of at least two terminal polymer blocks A and at least one intermediate polymer block B, said block A being a polymer block substantially derived from an aromatic vinyl compound, said block B being a polymer block substantially derived from isobutylene, the content of the aromatic vinyl compound being 5 to 50 % by weight, and the number average molecular weight of the block copolymer being 30,000 to 500,000, (b) 20 to 200 parts by weight of a tackifier resin, and (c) 5 to 150 parts by weight of a softener.

  一种增粘组合物，包括 (a) 100 重量份的嵌段共聚物，该嵌段共聚物由至少两个末端聚合物嵌段 A 和至少一个中间聚合物嵌段 B 组成，所述嵌段 A 是基本上由芳香族乙烯基化合物衍生的聚合物嵌段，所述嵌段 B 是基本上由异丁烯衍生的聚合物嵌段，芳香族乙烯基化合物的含量为 5%至 50%（重量百分比），嵌段共聚物的平均分子量为 30,000 至 500,000、 (b) 20 至 200 份（按重量计）增粘树脂，和 (c) 5 至 150 重量份的柔软剂。
• THERMOPLASTIC RESIN COMPOSITION
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0572667A1

  公开（公告）日：1993-12-08

  A thermoplastic resin composition having excellent resistances to heat, impact and solvent and improved compatibility, characterized by comprising 100 parts by weight of a thermoplastic resin (A) and 0.5 to 35 parts by weight of a block copolymer (B) having aromatic vinyl compound units and isobutylene units. Preferred examples thereof include a composition comprising 100 parts by weight of a polycarbonate as the component (A) and 5 to 20 parts by weight of a styrene/isobutylene block copolymer having a styrene unit content of 10 to 45 % and an average molecular weight of 50,000 to 400,000 as the component (B).

  一种热塑性树脂组合物，具有优异的耐热性、抗冲击性和耐溶剂性，并具有更好的相容性，其特征是由 100 份（重量）热塑性树脂（A）和 0.5 至 35 份（重量）具有芳香族乙烯基化合物单元和异丁烯单元的嵌段共聚物（B）组成。优选的例子包括一种组合物，其组分（A）为 100 重量份的聚碳酸酯，组分（B）为 5 至 20 重量份的苯乙烯/异丁烯嵌段共聚物，苯乙烯单元含量为 10 至 45%，平均分子量为 50,000 至 400,000。