| 1616726-75-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1616726-75-0
• 化学式: C₄₃H₄₈FeP₄
• 分子量: 744.596
• InChiKey: LCTKUXXOPCMMKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis(trimethylphosphine)iron(0) 、 DPE-phos 以 四氢呋喃 为溶剂， 反应 12.0h， 以65%的产率得到
  参考文献：
  名称：

  Synthesis and Catalytic Property of Iron Pincer Complexes Generated by C_sp³–H Activation

  摘要：

  When the diphosphinito PCP ligand (Ph2P-(C6H4))(2)CH2 (1) was treated with Fe(PMe3)(4) and Fe-Me-2(PMe3)(4), the C-sp(3)-H activation products [(Ph2P-(C6H4))(2)CH)Fe(H)(PMe3)(2) (2) and [(Ph2P(C6H4))(PhP-(C6H4)(2))CH]Fe(PMe3)(2) (3) were obtained at room temperature. The generation of product 3 underwent one C-sp(3)-H and one C-sp(2)-H bond activation process. The new iron hydride complex 2 showed good activity in the catalytic hydrosilylation of aldehydes and ketones by using (EtO)(3)SiH as the hydrogen source under mild conditions. Complexes 2 and 3 were characterized by spectroscopic methods and X-ray diffraction analysis.

  DOI：

  10.1021/om500429r
• 作为试剂：
  描述：

  2,6-二氯苯甲醛 在 三乙氧基硅烷 、 C₄₃H₄₈FeP₄ 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以89%的产率得到2,6-二氯苄醇
  参考文献：
  名称：

  Synthesis and Catalytic Property of Iron Pincer Complexes Generated by C_sp³–H Activation

  摘要：

  When the diphosphinito PCP ligand (Ph2P-(C6H4))(2)CH2 (1) was treated with Fe(PMe3)(4) and Fe-Me-2(PMe3)(4), the C-sp(3)-H activation products [(Ph2P-(C6H4))(2)CH)Fe(H)(PMe3)(2) (2) and [(Ph2P(C6H4))(PhP-(C6H4)(2))CH]Fe(PMe3)(2) (3) were obtained at room temperature. The generation of product 3 underwent one C-sp(3)-H and one C-sp(2)-H bond activation process. The new iron hydride complex 2 showed good activity in the catalytic hydrosilylation of aldehydes and ketones by using (EtO)(3)SiH as the hydrogen source under mild conditions. Complexes 2 and 3 were characterized by spectroscopic methods and X-ray diffraction analysis.

  DOI：

  10.1021/om500429r