| 151709-49-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 151709-49-8
• 化学式: C₃₈H₂₉ClN₅Ru*F₆P
• 分子量: 837.169
• InChiKey: JOOYUXDNLUOHDR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 6-苯基-2,2'-联吡啶 、 [trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)] 在 N-乙基吗啉 作用下， 以 溶剂黄146 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Solvent effects in the reactions of 6-phenyl-2,2′-bipyridine with ruthenium(II)

  摘要：

  The reaction of [Ru(tpy)Cl3] with the potentially cyclometallating ligand 6-phenyl-2,2'-bipyridine (HL) has been examined in a variety of solvents. In glacial acetic acid the ligand acts as a substituted 2,2'-bipyridine and reacts to give the complex cation [Ru(tpy)(HL)Cl]+, containing a bidentate N,N'-bonded HL ligand. The structure of this complex has been unambiguously established from its H-1 NMR spectrum. In contrast, the use of water as a solvent gives the cyclometallated complex cation [Ru(tpy)(L)]+. In methanol and butan-1-ol, mixtures of these two products are formed. The work has been extended to 2,2':6',2''-terpyridines with aromatic substituents in the 4' position and the complexes have been characterised by H-1 NMR, electronic and FAB mass spectroscopic techniques and also by cyclic voltammetry.

  DOI：

  10.1016/s0020-1693(00)82850-9