[(1,2-bis(diphenylphosphino)methane)(O,O'-diethyldithiophosphate)nickel(II)] perchlorate hydrate | 587023-00-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(1,2-bis(diphenylphosphino)methane)(O,O'-diethyldithiophosphate)nickel(II)] perchlorate hydrate
• CAS: 587023-00-5
• 化学式: C₂₉H₃₂NiO₂P₃S₂*ClO₄*H₂O
• 分子量: 745.781
• InChiKey: XWPUGYHWDBTZJX-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  双二苯基膦甲烷 、 nickel(II) bis(O,O'-diethyl dithiophosphate) 、 nickel(II) perchlorate hexahydrate 以 乙醇 为溶剂， 生成 [(1,2-bis(diphenylphosphino)methane)(O,O'-diethyldithiophosphate)nickel(II)] perchlorate hydrate
  参考文献：
  名称：

  O,O′-Dialkyldithiophosphato and O-alkyldithiophosphato nickel(II) complexes with bidentate P-donor ligands

  摘要：

  The following complexes, having the general formula [Ni(S2P{O}OR)(P-P)] {R = Et (1), i-Pr (2), P-P = dppe; R = Et (3), PP = 1,4-bis(diphenylphosphino)butane (dppb)}, [Ni(S2P{OR}(2))(P-P)]X {R = i-Pr (4), Et (5), P-P = 1,2-bis(diphenylphosphino)ethane (dppe); R =. Et, P-P = 1,1-bis(diphenylphosphino)methane (dppm) (6); X = ClO4-} and [Ni(S2P{OR}(2))(dppe)X] {R = i-Pr, X = NCS- (7); R = Et, X = Br- (8)}, have been synthesized. All the compounds have been characterized by elemental analyses, IR, UV-Vis, and P-31{H} NMR spectral studies, magnetic and conductivity measurements. Single crystal X-ray analysis revealed the molecular structures of [Ni(S2P{O}OEt)(dppe)] (1), [Ni(S2P{O}OEt)(dppE)](EtOH)-Et-. (3) and [Ni(S2P{OEt}(2))(dppe)]ClO4 (5), and confirmed a square-planar geometry around the nickel atoms. We have reason to believe that the coordination geometry in [Ni(S2P{OEt}(2))(dppe)Br](H2O)-H-. (8) is probably tetrahedral with monodentate coordinated (S2P{OEt}(2)) monoanion. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00101-3