biphenyl-decafluorobiphenyl co-crystal | 67986-81-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: biphenyl-decafluorobiphenyl co-crystal
• 英文别名: Biphenyl-Decafluorbiphenyl；1,1'-biphenyl;1,2,3,4,5-pentafluoro-6-(2,3,4,5,6-pentafluorophenyl)benzene
• CAS: 67986-81-6
• 化学式: C₁₂F₁₀*C₁₂H₁₀
• 分子量: 488.327
• InChiKey: PEVWEDOPNOLRSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  34.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  联苯 以 neat (no solvent, solid phase) 为溶剂， 反应 1.34h， 生成 biphenyl-decafluorobiphenyl co-crystal
  参考文献：
  名称：

  Solvent-free mechanochemical syntheses and reactions of π–π stacked arene–perfluoroarene co-crystals

  摘要：

  The mechanocheinical syntheses of four pi-pi stacked arene-perfluoroarene co-crystals comprising naphthalene or biphenyl and octafluoronaphthalene or decafluorobiphenyl are reported. The results of mechanochemical reactions between the co-crystals and the alternative arene or perfluoroarene demonstrate that exchange can occur, and also indicate the partner preferences of each reagent. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2015.04.004

文献信息

• Solvent-free mechanochemical synthesis of π–π stacked arene–perfluoroarene co-crystals
  作者：Graham C. Saunders、Tobias T. Wehr-Candler

  DOI：10.1016/j.jfluchem.2013.05.030

  日期：2013.9

  The 1:1 pi-pi stacked co-crystals of naphthalene-octafluoronaphthalene and biphenyl-decafluorobiphenyl were synthesized by manual grinding of arene and perfluoroarene. (C) 2013 Elsevier B.V. All rights reserved.