{Co(2,6-diacetylpyridine-monocarbohydrazone)Cl2}*H2O | 138645-27-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: {Co(2,6-diacetylpyridine-monocarbohydrazone)Cl2}*H2O
• CAS: 138645-27-9
• 化学式: C₁₀H₁₃Cl₂CoN₅O₂*H₂O
• 分子量: 383.16
• InChiKey: ZMEHMDITBXRMBZ-LFFBISCFSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-二乙酰基吡啶 、 碳酰肼 、 cobalt(II) chloride 以 乙醇 为溶剂， 生成 {Co(2,6-diacetylpyridine-monocarbohydrazone)Cl2}*H2O
  参考文献：
  名称：

  Template synthesis and thermal behaviour of some metal complexes of 2,6-diacetylpyridine-mono(carbohydrazone) ligand

  摘要：

  The chelating behaviour of neutral and deprotonated 2,6-diacetylpyridine-mono(carbohydrazone) (Hdapc) has been studied in some new complexes of Pd(II), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Ba(II) and UO2(VI). Spectroscopic, magnetic susceptibility and other analytical studies reveal that the ligand behaves as an NN-chelating agent in the neutral form and as an ONNO- or NNO-chelating agent in the deprotonated form. Molar conductance measurements indicate the presence of coordinated chloride ion and acetate group. The geometry of some of the metal complexes is also discussed. In addition, the thermal behaviour and the nature of the interaction of the water of crystallisation of some of the metal complexes have been studied using DTA, TG, X-ray powder diffraction, IR and solid electrical conductivity techniques.

  DOI：

  10.1016/0040-6031(91)87127-i