| 136150-81-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 136150-81-7
• 化学式: C₂₆H₂₄ClIP₂Pt
• 分子量: 755.862
• InChiKey: MCLXTWWVSKKCBZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.82
• 重原子数：
  31.0
• 可旋转键数：
  4.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum 在 四丁基高氯酸铵 、 氯苯 作用下， 以 氯苯 为溶剂， 生成 [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] 、 [PtI(C6H5)(1,2-bis(diphenylphosphino)ethane)] 、
  参考文献：
  名称：

  CX and CH cleavage by electrochemically generated non-linear [PtL2] complexes

  摘要：

  The electrochemical reduction of [PtX2L2] (X = halide, L2 = bidentate diphosphine: Ph2PCH2CH2PPh2, dppe; Cy2PCH2CH2PCy2, dcpe; Cy2P{CH2}3PCy2, dcpp) has been used as a method of generating non-linear [PtL2] compounds whose reactivity with substrates Ar-X (X = Cl, Br, CN, H, C=CPh) has been examined. Generation of [PtL2] (L2 = dppe or dcpe) in the presence of excess Ph - X (X = Cl, Br) produces [PtXPhL2] efficiently. Similarly, generation of [PtL2] (L2 = dppe or dcpe) in the presence of PhC=CPh results in trapping to form [PtL2(PhC=CPh)]. Generation of [PtL2] (L2 = dppe or dcpe) in the presence of PhCN or PhH results in indiscriminate reactions that do not produce tractable products. In contrast, reduction of [PtCl2(dcpp)] in CH3CN/C6H6/Bu4NClO4 produces [PtHPh(dcpp)] with considerable selectivity via aromatic C-H activation by [Pt(dcpp)]. At room temperature the complex [PtHPh(dcpp)] undergoes exchange with C6D6 to generate [PtD(C6D5)(dcpp)].

  DOI：

  10.1016/s0277-5387(00)86908-9