4'-Sulfo-biphenyl-3,4-dicarboxylic acid | 730936-89-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4'-Sulfo-biphenyl-3,4-dicarboxylic acid
• 英文别名: 4-(p-Sulfophenyl)phthalic acid；4-(4-sulfophenyl)phthalic acid
• CAS: 730936-89-7
• 化学式: C₁₄H₁₀O₇S
• 分子量: 322.295
• InChiKey: IYAGLDUDALGHGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  137
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4'-Sulfo-biphenyl-3,4-dicarboxylic acid 在 ammonium molybdate 、 copper (I) acetate 、 尿素 、 calcium carbonate 作用下， 以 水 为溶剂， 反应 5.08h， 生成 copper;4-[15,24,33-tris(4-sulfophenyl)-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(37),2,4(9),5,7,10,12(39),13(18),14,16,19,21,23,25,27,29,31(36),32,34-nonadecaen-6-yl]benzenesulfonic acid
  参考文献：
  名称：

  Synthesis and Properties of Sulfophenyl-Substituted Metal Phthalocyanine Complexes

  摘要：

  Sulfonation of 4-phenylphthalic acid gave 4-(p-sulfophenyl)phthalic acid triammonium salt which was used in the synthesis of tetra[4-(p-sulfophenyl)lphthalocyanine copper and cobalt complexes by the urea method. The products were characterized by elemental analyses and C-13 NMR, IR, and electronic spectra. Some specific features of the electronic spectra of sulfophenyl-substituted metal phthalocyanines were revealed, depending on the central metal atom, solvent nature., and concentration.

  DOI：

  10.1023/b:rugc.0000030405.21990.b5
• 作为产物：
  描述：

  [1,1'-联苯]-3,4-二甲酸 在 硫酸 作用下， 反应 4.0h， 生成 4'-Sulfo-biphenyl-3,4-dicarboxylic acid
  参考文献：
  名称：

  Synthesis and Properties of Sulfophenyl-Substituted Metal Phthalocyanine Complexes

  摘要：

  Sulfonation of 4-phenylphthalic acid gave 4-(p-sulfophenyl)phthalic acid triammonium salt which was used in the synthesis of tetra[4-(p-sulfophenyl)lphthalocyanine copper and cobalt complexes by the urea method. The products were characterized by elemental analyses and C-13 NMR, IR, and electronic spectra. Some specific features of the electronic spectra of sulfophenyl-substituted metal phthalocyanines were revealed, depending on the central metal atom, solvent nature., and concentration.

  DOI：

  10.1023/b:rugc.0000030405.21990.b5