2,5-Dianilino-1,4-benzochinon-3,6-dicarbonsaeure | 3645-74-7

• 分子结构分类: 有机化合物
• 英文名称: 2,5-Dianilino-1,4-benzochinon-3,6-dicarbonsaeure
• 英文别名: 2,5-dianilino-3,6-dioxo-1,4-cyclohexadiene-1,4-dicarboxylic acid；2,5-dianilino-3,6-dioxocyclohexa-1,4-diene-1,4-dicarboxylic acid
• CAS: 3645-74-7
• 化学式: C₂₀H₁₄N₂O₆
• 分子量: 378.341
• InChiKey: NDOIVBNLFLMVIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  133
• 氢给体数：
  4
• 氢受体数：
  8

文献信息

• Incorporation of quinacridone additives during quinacridone preparation
  申请人：Bayer Corporation

  公开号：EP0842987A2

  公开（公告）日：1998-05-20

  This invention relates to a process for the preparation of quinacridone pigments by (a) heating a reaction mixture comprising (i) a 2,5-dianilinoterephthalic acid, a 2,5-dianilino-6,13-dihydroterephthalic acid, or a 2,5-dianilino-3,6-dioxo-1,4-cyclohexadiene-1,4-dicarboxylic acid; (ii) about 0.1 to about 15 percent by weight, based on component (a)(i), of one or more sulfonyl-containing derivatives of 2,5-dianilinoterephthalic acid, 2,5-dianilino-6,13-dihydroterephthalic acid, and/or 2,5-dianilino-3,6-dioxo-1,4-cyclohexadiene-1,4-dicarboxylic acid; and (iii) about 3 to about 20 parts by weight, per part of component (a)(i), of a dehydrating agent, with the proviso that if either component (a)(i) or component (a)(ii) is a 2,5-dianilino-6,13-dihydroterephthalic acid or derivative thereof, reaction step (a) additionally comprises an oxidation step; (b) drowning the reaction mixture from step (a) with a liquid in which the quinacridone pigment is substantially insoluble; and (c) isolating the quinacridone pigment.

  本发明涉及一种通过以下方法制备喹吖啶酮颜料的工艺 (a) 加热包含以下成分的反应混合物 (i) 2,5-二苯胺对苯二甲酸、2,5-二苯胺-6,13-二氢对苯二甲酸或 2,5-二苯胺-3,6-二氧代-1,4-环己二烯-1,4-二羧酸； (ii) 以组分(a)(i)为基准，约 0.1%至约 15%（按重量计）的 2,5-二苯胺对苯二甲酸、2,5-二苯胺-6,13-二氢对苯二甲酸和/或 2,5-二苯胺-3,6-二氧代-1,4-环己二烯-1,4-二羧酸的一种或多种含磺酰基的衍生物；以及 (iii) 每份(a)(i)组分约 3 至约 20 重量份的脱水剂、 但如果组分(a)(i)或组分(a)(ii)是 2,5-二苯胺-6,13-二氢对苯二甲酸或其衍生物，反应步骤(a)还包括氧化步骤； (b) 用一种喹吖啶酮颜料基本上不溶于其中的液体淹没步骤(a)的反应混合物；以及 (c) 分离喹吖啶酮颜料。
• Organic pigment compositions
  申请人：Bayer Corporation

  公开号：EP0851006A1

  公开（公告）日：1998-07-01

  This invention relates to pigment compositions comprising an organic pigment treated with about 0.1 to about 20% by weight, based on the organic pigment, of an N-heteroarylamidomethyl pigment derivative having the formula (I) wherein Qrepresents an organic pigment moiety, NHetrepresents a nitrogen-containing heteroaromatic group attached at a ring nitrogen atom to the carbonyl function of the amidomethyl linking group, and nis from 1 to 4.

  本发明涉及一种颜料组合物，该颜料组合物包含一种有机颜料，该有机颜料用约 0.1%至约 20%（按有机颜料重量计）的 N-杂芳基酰胺甲基颜料衍生物处理，该衍生物具有式 (I) 其中 Q 代表有机颜料分子、 NHet 代表在环状氮原子上与酰胺甲基连接基团的羰基官能团相连的含氮杂芳香族基团，以及 n 为 1 至 4。
• Microwave syntheses of quinacridones, 6, 13-dihydroquinacridones and 6, 13-quinacridonequinones
  申请人：Bayer Corporation

  公开号：EP0905199A3

  公开（公告）日：1999-10-27

  This invention relates to a process for the preparation of quinacridone pigments by (a) exposing a reaction mixture containing (i) 2,5-dianilinoterephthalic acid, 2,5-dianilino-3,6-dihydroterephthalic acid, 2,5-dianilino-3,6-dioxo-1,4-cyclohexadiene-1,4-dicarboxylic acid, and/or derivatives thereof,(ii) about 3 to about 20 parts by weight, per part of component (a)(i), of a dehydrating agent, and(iii) 0 to about 20 parts by weight, per part of component (a)(i), of a pigment additive, to microwave radiation under conditions that raise the bulk temperature of the reaction mixture to no more than about 250°C, with the proviso that if component (a)(i) is a 2,5-dianilino-3,6-dihydroterephthalic acid or derivative thereof, reaction step (a) additionally comprises an oxidation step;(b) drowning the reaction mixture in about 3 to about 15 parts by weight, per part of component (a)(i), of a liquid in which the quinacridone pigment is substantially insoluble;(c) isolating the quinacridone pigment; and(d) optionally, conditioning the pigment.

  本发明涉及一种通过以下方法制备喹吖啶酮颜料的工艺 (a) 将含有以下物质的反应混合物曝晒 (i) 2,5-二苯胺对苯二甲酸、2,5-二苯胺-3,6-二氢对苯二甲酸、2,5-二苯胺-3,6-二氧代-1,4-环己二烯-1,4-二羧酸和/或其衍生物，(ii) 每份(a)(i)组分重量计约 3 至约 20 份脱水剂，和(iii) 每份(a)(i)组分重量计 0 至约 20 份颜料添加剂、(iii)每份组分(a)(i)0 至约 20 重量份的颜料添加剂，在将反应混合物的体积温度升至不超过约 250°C 的条件下进行微波辐射，但如果组分(a)(i)是 2,5-二苯胺基-3,6-二氢对苯二甲酸或其衍生物，则反应步骤(a)还包括一个氧化步骤；(b) 以每份(a)(i)组分的重量计，将反应混合物浸入约 3 至约 15 份喹吖啶酮颜料基本上不溶于其中的液体中； (c) 分离喹吖啶酮颜料；以及 (d) 可选择地调节颜料。
• Pigment derivatives for waterborne coatings
  申请人：Bayer Corporation

  公开号：EP0953609A2

  公开（公告）日：1999-11-03

  This invention relates to pigment derivatives having the formula wherein Qrepresents an organic pigment moiety; Xis -SO2- or -CO-; Alkis C2-C8 alkylene or substituted C2-C8 alkylene; mis an integer of from 1 to 4; n and pare independently integers of from 2 to 6. This invention further relates to the treatment of organic pigments with such pigment derivatives and the use of such treated pigments in coating compositions.

  本发明涉及具有以下式子的颜料衍生物 式中 Q 代表有机颜料分子； X是-SO2-或-CO-； 烷是 C2-C8 亚烷基或取代的 C2-C8 亚烷基； mis为1至4的整数； n和pare独立地为2至6的整数。 本发明进一步涉及用此类颜料衍生物处理有机颜料以及在涂料组合物中使用此类处理过的颜料。
• JPH10158536A
  申请人：——

  公开号：JPH10158536A

  公开（公告）日：1998-06-16