| 1449684-99-4

• CAS: 1449684-99-4
• 化学式: C₃₄H₆₄Li₄N₈
• 分子量: 612.7
• InChiKey: WMSWFYSYPQEBJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cyclohexyl-pyrrol-2-ylmethyl-amine 、 四甲基乙二胺 在 正丁基锂 作用下， 以 正己烷 为溶剂， 反应 8.0h， 以65%的产率得到
  参考文献：
  名称：

  2-Aminopyrrolyl Dilithium Compounds: Synthesis, Structural Diversity, and Catalytic Activity for Amidation of Aldehydes with Amines

  摘要：

  Five dilithium compounds containing bidentate dianionic pyrrolyl ligands, [{2-(CH3NCH2)C4H3N}Li-2(TMEDA)(3)] (1), {[mu-eta(5)-2- [ CH3CH2NCH2] C4H3N]Li-2(TMEDA)}(2) (2), {[Pris eta(5):eta(1)-2-[(CH3)(3)CNCH2]C4H3N]Li-2(TMEDA)}(2) (3), {[eta(5)-2-[(CH3)(2)CHNCH2]C4H3N]Li-2 (TMEDA)}(2) (4), and {[eta(5)-2-[(CH2)(5)CHNCH2]C4H3N1Li2(TMEDA)}(2) (5), were synthesized, and their structural features were provided. Compounds 1-5 were proved to be a series of efficient catalysts for amidation reactions of aldehydes with amines in good to excellent yields under mild conditions.

  DOI：

  10.1021/om4006609