(3Z,6Z)-1-chloro-3,6-nonadiene | 1455183-96-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: (3Z,6Z)-1-chloro-3,6-nonadiene
• 英文别名: (3Z,6Z)-1-chloronona-3,6-diene；(3Z,6Z)-nonadien-1-yl chloride
• CAS: 1455183-96-6
• 化学式: C₉H₁₅Cl
• 分子量: 158.671
• InChiKey: QQGLLKQILKZMEK-CWWKMNTPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (3Z,6Z)-1-chloro-3,6-nonadiene 在 盐酸 、 4-二甲氨基吡啶 、 乙酸酐 、 magnesium 作用下， 以 四氢呋喃 、 甲醇 、 甲苯 为溶剂， 反应 4.0h， 生成 (3E,8Z,11Z)- 十四碳三烯乙酸酯
  参考文献：
  名称：

  NOVEL METHOD FOR MANUFACTURING TOMATO LEAFMINER PHEROMONE COMPONENTS

  摘要：

  The present invention relates to a method for synthesising a pheromone of general formula selected from the group comprising compounds (I) and (I′), alone or in admixture: (I) (I′) comprising reacting (2E)-pentene-1,5-diyl diacetate with at least one Grignard reagent in the presence of a copper-based catalyst. The method according to the invention is particularly applicable to the selective synthesis of tomato leafminer (Tuta absolute) pheromone comprising: (3E,8Z,11Z)-tetradecatrien-1-yl acetate and (3E,8Z)-tetradecadien-1-yl acetate.

  公开号：

  US20240140902A1
• 作为产物：
  描述：

  (Z,z)-3,6-壬二烯-1-醇 在 吡啶 、 氯化亚砜 作用下， 以 甲苯 为溶剂， 生成 (3Z,6Z)-1-chloro-3,6-nonadiene
  参考文献：
  名称：

  WO2023/65203

  摘要：

  公开号：

文献信息

• METHOD FOR PRODUCING REDUCED HALIDE COMPOUND HAVING UNDERGONE REDUCTION OF CARBON-CARBON UNSATURATED BOND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20190322607A1

  公开（公告）日：2019-10-24

  A halide compound having one or more carbon-carbon unsaturated bonds is catalytically reduced with substantially no dehalogenation to produce a reduced halide compound in which at least one of the one or more unsaturated bonds is reduced. Specifically provided is a method for producing a reduced halide compound including steps of: reacting a nickel compound, a zinc compound, and a borohydride compound in a solvent to obtain a reduction catalyst; and subjecting a halide compound having one or more carbon-carbon unsaturated bonds to catalytic reduction in the presence of the reduction catalyst to reduce at least one of the one or more carbon-carbon unsaturated bonds to thereby obtain a reduced halide compound.

  一种卤化物化合物，其具有一个或多个碳-碳不饱和键，经催化还原而几乎不发生去卤反应，以产生一个减少的卤化物化合物，其中至少一个或多个不饱和键被还原。具体提供了一种生产减少的卤化物化合物的方法，包括以下步骤：在溶剂中反应镍化合物、锌化合物和硼氢化物化合物以获得还原催化剂；并在还原催化剂存在的情况下，将具有一个或多个碳-碳不饱和键的卤化物化合物进行催化还原，以减少至少一个或多个碳-碳不饱和键，从而获得减少的卤化物化合物。
• Method for producing reduced halide compound having undergone reduction of carbon-carbon unsaturated bond
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10676417B2

  公开（公告）日：2020-06-09

  A halide compound having one or more carbon-carbon unsaturated bonds is catalytically reduced with substantially no dehalogenation to produce a reduced halide compound in which at least one of the one or more unsaturated bonds is reduced. Specifically provided is a method for producing a reduced halide compound including steps of: reacting a nickel compound, a zinc compound, and a borohydride compound in a solvent to obtain a reduction catalyst; and subjecting a halide compound having one or more carbon-carbon unsaturated bonds to catalytic reduction in the presence of the reduction catalyst to reduce at least one of the one or more carbon-carbon unsaturated bonds to thereby obtain a reduced halide compound.

  具有一个或多个碳-碳不饱和键的卤化物化合物在催化还原过程中基本上不发生脱卤反应，从而产生一种还原型卤化物化合物，其中至少一个或多个不饱和键被还原。具体而言，提供了一种生产还原型卤化物化合物的方法，包括以下步骤：将镍化合物、锌化合物和硼氢化合物在溶剂中反应，得到还原催化剂；在还原催化剂存在下，将具有一个或多个碳碳不饱和键的卤化物化合物进行催化还原，以还原一个或多个碳碳不饱和键中的至少一个，从而得到还原型卤化物化合物。