2-(N-[2-(dimethylamino)ethyl]iminomethyl)-6-[N,N-di(2-pyridylmethyl)aminomethyl]-4-methylphenol | 192819-70-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(N-[2-(dimethylamino)ethyl]iminomethyl)-6-[N,N-di(2-pyridylmethyl)aminomethyl]-4-methylphenol
• 英文别名: 2-[[Bis(pyridin-2-ylmethyl)amino]methyl]-6-[2-(dimethylamino)ethyliminomethyl]-4-methylphenol
• CAS: 192819-70-8
• 化学式: C₂₅H₃₁N₅O
• 分子量: 417.554
• InChiKey: HZJOKUNNRIMREE-UHFFFAOYSA-N

物化性质

• 沸点：
  544.4±50.0 °C(Predicted)
• 密度：
  1.09±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  31
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  64.8
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-(N-[2-(dimethylamino)ethyl]iminomethyl)-6-[N,N-di(2-pyridylmethyl)aminomethyl]-4-methylphenol 、 sodium perchlorate 、 copper(II) acetate monohydrate 以 甲醇 为溶剂， 以66.5%的产率得到
  参考文献：
  名称：

  Site Specificity of Metal Ions in Heterodinuclear Complexes Derived from an “End-Off” Compartmental Ligand

  摘要：

  A phenol-based "end-off" compartmental ligand,2-{N-[2-(dimethylamino)ethyl]iminomethyl}-6[NN-di(2-pyridylmethyl)-aminomethyl]-4-methylphenol (HL), having a bidentate arm and a tridentate arm attached to the 2 and 6 positions of the phenolic ring, has afforded the following heterodinuclear (MaMbII)-M-II complexes: [CuM(L)(AcO)(2)]ClO4 (M = Mn (1), Fe (2), Co (3), Ni (4), Zn (5)), [ZnM(L)(AcO)(2)]ClO4 (M = Co (6), Ni (7)), and [CuNi(L)(AcO)(NCS)(2)] (8). 1.MeOH (1'), 2.MeOH (2'), 3.MeOH (3'), 4.MeOH (4'), 5.MeOH (5'), and 7.MeOH (7') are isostructural and have a heterodinuclear core bridged by the phenolic oxygen atom of L- and two acetate groups. In 1'-5' the Cull is bound to the bidentate arm and has a square-pyramidal geometry with one acetate oxygen at the apical site. The M-II is bound to the tridentate arm and has a six-coordinate geometry together with two acetate oxygen atoms. In the case of 7' the Zn is bound to the bidentate arm and the Ni is bound to the tridentate arm. 8.2-PrOH (8') has a dinuclear core bridged by the phenolic oxygen atom of L- and one acetate group. The Cu bound to the bidentate arm has a square-pyramidal geometry with an isothiocyanate group at the apical site. The Ni bound to the tridentate arm has a six-coordinate geometry with further coordination of an isothiocyanate group. The site specificity of the metal ions is discussed together with the crystal structure of [Cu-4(L)(2)(AcO)(3)](ClO4)(3).H2O (9) prepared in this work.

  DOI：

  10.1021/ic020002f

文献信息

• Hydrolytic Activity of A Fe^IIIZn^IIComplex toward Di(<i>p</i>-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiestelase
  作者：Hironobu Machinaga、Kanako Matsufuji、Masaaki Ohba、Masahito Kodera、Hisashi Okawa

  DOI：10.1246/cl.2002.716

  日期：2002.7

  A FeIIIZnIII complex, [FeZn(L)(AcO)3]BPh4·H2O, of 2-N-[2-(dimethylamino)ethyl]iminomethyl}-6-[N,N-di(2-pyridyl-methyl)aminomethyl]-4-methylphenolate (L-) hydrolyses tri(p-nitrophenyl) phosphate (TNP) into di(p-nitrophenyl) phosphate (DNP-) and DNP- into mono(p-nitrophenyl) phosphate (MNP2-) in aqueous DMF.

  2-N-[2-(二甲基氨基)乙基]亚氨基甲基}-6-[N、在 DMF 水溶液中，[FeZn(L)(AcO)3]BPh4-H2O、2-N-[2-(二甲基氨基)乙基]亚氨甲基}-6-[N, N-二(2-吡啶基甲基)氨基甲基]-4-甲基苯酚（L-）会将磷酸三（对硝基苯基）酯（TNP）水解为磷酸二（对硝基苯基）酯（DNP-），并将 DNP-水解为磷酸单（对硝基苯基）酯（MNP-）。