| 693233-60-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 693233-60-2
• 化学式: C₁₈H₂₄BCrN
• 分子量: 317.202
• InChiKey: UHIRTNBCLYPUNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 二氯甲烷 为溶剂， 生成 双苯铬
  参考文献：
  名称：

  Synthesis and Structure of [Cr{(η⁶-C₆H₅)₂B{NtBu(SiMe₃)}}] and [Cr{(η⁶-C₆H₅)₂(BNMe₂)₂}], the First Boron-Bridged Metalloarenophanes

  摘要：

  Reaction of [Cr(eta(6)-C6H5Li)(2)].tmen with (RR')-NBCl2 (R = R' = SiMe3; R = R' = iPr; R = SiMe3, R' = tBu) and B2Br2(NMe2)(2), respectively, in hexane yielded the strained [1]borachromoarenophanes [Cr{(eta(6)- C6H5)(2)-BNRR'}] (4a-c; R = R' = SiMe3; R = R' = iPr; R = SiMe3, R' = tBu) and [2]borachromoarenophanes [Cr-{(eta(6)- C6H5)(2)(BNMe2)(2)}] (5), respectively, in moderate yields as dark red solids; compounds 4c and 5 were structurally characterized. 4c exhibits the largest arenearene tilt angle (26.6(3)degrees) reported for any [n]metal-loarenophane.

  DOI：

  10.1021/om049872q
• 作为产物：
  描述：

  dilithiobis(benzene)chromium*N,N,N',N'-tetramethylethylenediamine 、 二氯(二异丙基氨基)硼烷 以 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Structure of [Cr{(η⁶-C₆H₅)₂B{NtBu(SiMe₃)}}] and [Cr{(η⁶-C₆H₅)₂(BNMe₂)₂}], the First Boron-Bridged Metalloarenophanes

  摘要：

  Reaction of [Cr(eta(6)-C6H5Li)(2)].tmen with (RR')-NBCl2 (R = R' = SiMe3; R = R' = iPr; R = SiMe3, R' = tBu) and B2Br2(NMe2)(2), respectively, in hexane yielded the strained [1]borachromoarenophanes [Cr{(eta(6)- C6H5)(2)-BNRR'}] (4a-c; R = R' = SiMe3; R = R' = iPr; R = SiMe3, R' = tBu) and [2]borachromoarenophanes [Cr-{(eta(6)- C6H5)(2)(BNMe2)(2)}] (5), respectively, in moderate yields as dark red solids; compounds 4c and 5 were structurally characterized. 4c exhibits the largest arenearene tilt angle (26.6(3)degrees) reported for any [n]metal-loarenophane.

  DOI：

  10.1021/om049872q

文献信息

• Synthesis and Structure of [Cr{(η⁶-C₆H₅)₂B{N<i>t</i>Bu(SiMe₃)}}] and [Cr{(η⁶-C₆H₅)₂(BNMe₂)₂}], the First Boron-Bridged Metalloarenophanes
  作者：Holger Braunschweig、Melanie Homberger、Chunhuas Hu、Xiaolai Zheng、Emanuel Gullo、Guy Clentsmith、Matthias Lutz

  DOI：10.1021/om049872q

  日期：2004.4.1

  Reaction of [Cr(eta(6)-C6H5Li)(2)].tmen with (RR')-NBCl2 (R = R' = SiMe3; R = R' = iPr; R = SiMe3, R' = tBu) and B2Br2(NMe2)(2), respectively, in hexane yielded the strained [1]borachromoarenophanes [Cr(eta(6)- C6H5)(2)-BNRR'}] (4a-c; R = R' = SiMe3; R = R' = iPr; R = SiMe3, R' = tBu) and [2]borachromoarenophanes [Cr-(eta(6)- C6H5)(2)(BNMe2)(2)}] (5), respectively, in moderate yields as dark red solids; compounds 4c and 5 were structurally characterized. 4c exhibits the largest arenearene tilt angle (26.6(3)degrees) reported for any [n]metal-loarenophane.