(η2-C70)Pd(DIOP) | 275356-96-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (η2-C70)Pd(DIOP)
• CAS: 275356-96-2
• 化学式: C₁₀₁H₃₂O₂P₂Pd
• 分子量: 1445.73
• InChiKey: ODVFVMAKRYTQRP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.73
• 重原子数：
  106.0
• 可旋转键数：
  4.0
• 环数：
  44.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (η2-C70)Pd(DIOP) 、 diisopropoxyphosphoryl 生成
  参考文献：
  名称：

  Metal-containing fullerenyl radicals: generation in solution and EPR study

  摘要：

  Photolysis of cis-(CF3)(2)CF-Hg-Pt(PPh3),-CH=CPh2 in a saturated toluene solution of C-60 has generated the platinum-centered free radical, which adds to C-60 to give a spin-adduct cis-Ph2C=CH-Pt(PPh3)(2)-C-60(.) fully characterized by EPR spectroscopy. Phosphorylfullerenyl radicals containing a eta(2)-coordinated ML2 moiety have been prepared, starting from phosphorylfullerenyl radical dimers. The metal complex (eta(2)-C-70)Pd[(+)DIOP] has been shown to undergo the partial rupture of M-C bonding as a consequence of the phosphoryl radical attack on the metal atom to give three regioisomers of metal-containing fullerenyl radicals. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00659-2