[Zn(N,N'-di(o-oxyphenyl)terephthalaldehydediimine)(H2O)2]n | 375396-67-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Zn(N,N'-di(o-oxyphenyl)terephthalaldehydediimine)(H2O)2]n
• CAS: 375396-67-1
• 化学式: C₂₀H₁₈N₂O₄Zn
• 分子量: 415.764
• InChiKey: XFDUBIPWRYVWDM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-[1,4-亚苯基二(次甲基次氮基)]双酚 、 zinc diacetate 以 N,N-二甲基甲酰胺 为溶剂， 以15%的产率得到[Zn(N,N'-di(o-oxyphenyl)terephthalaldehydediimine)(H2O)2]n
  参考文献：
  名称：

  COORDINATION CHAIN POLYMERS OF SOME TRANSITION METALS WITH SCHIFF BASE

  摘要：

  The Schiff base derived from terephthalaldehyde and o-aminophenol is known as N,N'-di(o-hydroxyphenyl)terephthalaidehydediimine and is termed here as H2SB. The polychelates of this Schiff base having the general formula [M(SB)(H2O)(2)](n) [where M=Mn(II), Co(Il), Ni(II), Cu(II), Zn(II) and Cd(II)] have been synthesized and characterized on the basis of elemental analyses, infrared spectra. electronic spectra, magnetic measurements and thermogravimetric analyses. The Schiff base act as uninegative bidentate ligand and bonding occurs through the hydroxyl oxygen and nitrogen atoms. An octahedral geometry has been assigned to all of the prepared polychelates.

  DOI：

  10.1081/sim-100105259