N-phenethyl diacrylimide | 916730-76-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-phenethyl diacrylimide
• 英文别名: N-(2-phenylethyl)-N-prop-2-enoylprop-2-enamide
• CAS: 916730-76-2
• 化学式: C₁₄H₁₅NO₂
• 分子量: 229.279
• InChiKey: JTMSTEQCHKYZFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-phenethyl diacrylimide 在 氢氧化钾 作用下， 以 乙腈 为溶剂， 反应 18.33h， 以65%的产率得到(1R,2S)-2-(2-phenylethylcarbamoyl)cyclobutane-1-carboxylic acid
  参考文献：
  名称：

  Synthesis and evaluation of the first cis-cyclobutane-containing receptor for lipid A

  摘要：

  首次合成了含有顺式-1,3-二取代环丁烷环的设计型受体。该分子能够与二磷酸脂质A（革兰氏阴性菌细胞膜的保守部分，也是导致败血性休克的致病因子）结合，其亲和力与先前描述的基于三环烷烃的脂质A结合化合物相当。

  DOI：

  10.1039/b610727c
• 作为产物：
  描述：

  2-苯乙胺 、 丙烯酰氯 在 2,6-二甲基吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 17.0h， 以73%的产率得到N-phenethyl diacrylimide
  参考文献：
  名称：

  Synthesis and evaluation of the first cis-cyclobutane-containing receptor for lipid A

  摘要：

  首次合成了含有顺式-1,3-二取代环丁烷环的设计型受体。该分子能够与二磷酸脂质A（革兰氏阴性菌细胞膜的保守部分，也是导致败血性休克的致病因子）结合，其亲和力与先前描述的基于三环烷烃的脂质A结合化合物相当。

  DOI：

  10.1039/b610727c

文献信息

• MODIFIED CONJUGATED DIENE-BASED POLYMER, METHOD FOR PRODUCING SAME, AND RUBBER COMPOSITION COMPRISING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3851465A1

  公开（公告）日：2021-07-21

  The present invention relates to a modified conjugated diene-based polymer having controlled degree of branching, excellent affinity with a filler, and excellent processability properties and compounding properties, a method for preparing the same, and a rubber composition including the same. The modified conjugated diene-based polymer is prepared using a modifier represented by Formula 1 and may control the degree of branching of a polymer chain and improve processability properties and abrasion resistance, and affinity with a filler is excellent by including a functional group derived from the modifier in at least one terminal of the polymer chain. The compounding properties of a rubber composition including the same may be improved.

  本发明涉及一种改性共轭二烯基聚合物，其支化程度可控，与填料的亲和性极佳，加工性能和混炼性能优异，还涉及一种制备方法，以及一种包含该聚合物的橡胶组合物。改性共轭二烯烃基聚合物是使用式 1 所代表的改性剂制备的，可控制聚合物链的支化程度，改善加工性能和耐磨性，并且通过在聚合物链的至少一个末端加入由改性剂衍生的官能团，与填料的亲和性极佳。此外，通过在聚合物链的至少一个末端加入由改性剂衍生的官能团，还可提高与填料的亲和性，从而改善橡胶组合物的混炼性能。
• Liquid polymerizable composition comprising an anhydride derivative monomer and mineral nanoparticles dispersed therein, and its use to manufacture an optical article
  申请人：ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE)

  公开号：US10428221B2

  公开（公告）日：2019-10-01

  A liquid polymerizable composition including an anhydride derivative monomer with mineral nanoparticles homogeneously dispersed therein, as well as its use for the preparation of a transparent polymeric material having a high refractive index and its use in the optical field.

  一种液态可聚合组合物，包括均匀分散有矿物纳米颗粒的酸酐衍生物单体，以及该组合物在制备具有高折射率的透明聚合材料中的用途和在光学领域中的应用。
• LIQUID POLYMERIZABLE COMPOSITION COMPRISING AN ANHYDRIDE DERIVATIVE MONOMER AND MINERAL NANOPARTICLES DISPERSED THEREIN, AND ITS USE TO MANUFACTURE AN OPTICAL ARTICLE
  申请人：Essilor International (Compagnie Générale d'Optique)

  公开号：EP3083842B1

  公开（公告）日：2017-11-29
• Modified Conjugated Diene-Based Polymer, Method For Preparing The Same And Rubber Composition Comprising The Same
  申请人：LG Chem, Ltd.

  公开号：US20220127405A1

  公开（公告）日：2022-04-28

  The present invention relates to a modified conjugated diene-based polymer having controlled degree of branching, excellent affinity with a filler, and excellent processability properties and compounding properties, a method for preparing the same, and a rubber composition including the same. The modified conjugated diene-based polymer is prepared using a modifier represented by Formula 1 to include a functional group derived from the modifier in at least one terminal of the polymer chain: 1—wherein R 1 to R 3 and n are described herein.
• [EN] LIQUID POLYMERIZABLE COMPOSITION COMPRISING AN ANHYDRIDE DERIVATIVE MONOMER AND MINERAL NANOPARTICLES DISPERSED THEREIN, AND ITS USE TO MANUFACTURE AN OPTICAL ARTICLE<br/>[FR] COMPOSITION LIQUIDE POLYMÉRISABLE COMPRENANT UN MONOMÈRE DÉRIVÉ D'ANHYDRIDE ET DES NANOPARTICULES MINÉRALES DISPERSÉES DANS CELUI-CI, ET SON UTILISATION POUR FABRIQUER UN ARTICLE OPTIQUE
  申请人：ESSILOR INT

  公开号：WO2015092466A1

  公开（公告）日：2015-06-25

  The invention concerns a liquid polymerizable composition comprising an anhydride derivative monomer with mineral nanoparticles homogeneously dispersed therein, as well as its use for the preparation of a transparent polymeric material having a high refractive index and its use in the optical field.