2-(1-phenylcyclopropyl)ethyl acetate | 69096-86-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(1-phenylcyclopropyl)ethyl acetate
• CAS: 69096-86-2
• 化学式: C₁₃H₁₆O₂
• 分子量: 204.269
• InChiKey: VNBGSIHVOSHAJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(1-phenylcyclopropyl)ethyl acetate 在 氢氧化钾 、 三苯基膦 作用下， 以 甲醇 、 四氯化碳 、 N,N-二甲基甲酰胺 、 苯 为溶剂， 反应 62.0h， 生成
  参考文献：
  名称：

  The intramolecular electron transfer reactions of N-Alkylcyclopropyl phthalimides

  摘要：

  N-Alkylcyclopropyl phthalimides 5 and 6 were photolyzed to afford spiro lactams 17, 18 and 20-24. These products arise via an intramolecular electron transfer reaction between the phthalimide and the phenylcyclopropane portions of the molecule. The resulting radical anion attacks the phenylcyclopropane radical cation which is followed by radical-radical coupling to afford the observed photoadducts. In addition, the isolation of olefin 19 offers additional proof that the attack of the radical anion onto the radical cation is a stepwise process rather than a concerted one. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00108-7
• 作为产物：
  描述：

  二碘甲烷 、 γ-亚甲基苯丙醇乙酸酯 在 copper(l) chloride 、 锌 作用下， 以 乙醚 为溶剂， 反应 70.0h， 以55%的产率得到2-(1-phenylcyclopropyl)ethyl acetate
  参考文献：
  名称：

  The intramolecular electron transfer reactions of N-Alkylcyclopropyl phthalimides

  摘要：

  N-Alkylcyclopropyl phthalimides 5 and 6 were photolyzed to afford spiro lactams 17, 18 and 20-24. These products arise via an intramolecular electron transfer reaction between the phthalimide and the phenylcyclopropane portions of the molecule. The resulting radical anion attacks the phenylcyclopropane radical cation which is followed by radical-radical coupling to afford the observed photoadducts. In addition, the isolation of olefin 19 offers additional proof that the attack of the radical anion onto the radical cation is a stepwise process rather than a concerted one. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00108-7